or the number of systems changing in unit time is proportional to the
number unchanged at that time.
In the case of recovery of activity, after an active product has been
removed, the number of systems changing in unit time, when radio-active
equilibrium is produced, is equal to λ_N₀_. This must be equal to the
number _q₀_ of new systems applied in unit time, or
_q₀_ = λ_N₀_,
_q₀_
and λ = ------;
_N₀_
λ has thus a distinct physical meaning, and may be defined as the
proportion of the total number of systems present which change per
second. It has different values for different types of active matter,
but is invariable for any particular type of matter. For this reason, λ
will be termed the “_radio-active constant_” of the product.
We are now in a position to discuss with more physical definiteness the
gradual growth of Th X in thorium, after the Th X has been completely
removed from it. Let _q₀_ particles of Th X be produced per second by
the thorium, and let _N_ be the number of particles of Th X present at
any time _t_ after the original Th X was removed. The number of
particles of Th X which change every second is λ_N_, where λ is the
radio-active constant of Th X. Now, at any time during the process of
recovery, the rate of increase of the number of particles of Th X = the
rate of production − the rate of change; that is
_dN_
------ = _q₀_ − λ_N_.
_dt_
The solution of this equation is of the form
$$ N = ae^{–λt} + b $$,
where _a_ and _b_ are constants.
Now when _t_ is very great, the number of particles of Th X present
reach a maximum value _N₀_.
Thus, since _N_ = _N₀_ when _t_ = infinity,
_b_ = _N₀_;
since _N_ = 0 when _t_ = 0,
_a_ + _b_ = 0;
hence _b_ = -_a_ = _N₀_,
and the equation becomes
$$ \frac {N} {N₀} = 1 − e^{–λt} $$ .
This is equivalent to the equation already obtained in section 130,
since the intensity of the radiation is always proportional to the
number of particles present.
=134. Influence of conditions on the rate of decay.= Since the activity
of any product, at any time, may be taken as a measure of the rate at
which chemical change takes place, it may be used as a means of
determining the effect of conditions on the changes occurring in
radio-active matter. If the rate of change should be accelerated or
retarded, it is to be expected that the value of the radio-active
constant λ will be increased or decreased, _i.e._ that the decay curve
will be different under different conditions.
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