The variation of luminosity with different distances between the screens
is to be expected. The amount of excited activity deposited on the
boundaries is proportional to the amount of emanation present. Since the
emanation is equally distributed, the amount of excited activity
deposited on the screens, due to the emanation between them, varies
directly as the distance, provided the distance between the screens is
small compared with their dimensions. Such a result would also follow if
the phosphorescence were due to the radiation from the emanation itself,
provided that the pressure of the gas was low enough to prevent
absorption of the radiation from the emanation in the gas itself between
the screens.
Measurements of Emanating Power.
=149. Emanating power.= The compounds of thorium in the solid state vary
very widely in the amount of emanation they emit under ordinary
conditions. It is convenient to use the term _emanating power_ to
express the amount of emanation given off per second by one gram of the
compound. Since, however, we have no means of determining absolutely the
amount of emanation present, all measurements of emanating power are of
necessity comparative. In most cases, it is convenient to take a given
weight of a thorium compound, kept under conditions as nearly as
possible constant, and to compare the amount of emanation of the
compound to be examined with this standard.
In this way comparisons of the emanating power of thorium compounds have
been made by Rutherford and Soddy[244], using an apparatus similar to
that shown in Fig. 51 on page 240.
A known weight of the substance to be tested was spread on a shallow
dish, placed in the glass tube _C_. A stream of dry dust-free air, kept
constant during all the experiments, was passed over the compound and
carried the emanation into the testing vessel. After ten minutes
interval, the current due to the emanation in the testing vessel reached
a constant value. The compound was then removed, and the standard
comparison sample of equal weight substituted; the saturation current
was observed when a steady state was again reached. The ratio of these
two currents gives the ratio of the emanating power of the two samples.
It was found experimentally that, for the velocities of air current
employed, the saturation current in the testing vessel was directly
proportional to the weight of thorium, for weights up to 20 grams. This
is explained by the supposition that the emanation is removed by the
current of air from the mass of the compound, as fast as it is formed.
Let _i₁_ = saturation current due to a weight ω₁ of the standard,
_i₂_ = „ „ „ „ ω₂ of the sample to be tested.
(emanating power of specimen) _i₂_ ω₁
Then ---------------------------- = ---- ---
(emanating power of standard) _i₁_ ω₂
By means of this relation the emanating power of compounds which are not
of equal weight can be compared.
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