The method of examination of the radiations from the emanations has been
given in some detail, as the results are of considerable importance in
the discussion, which will be given later in chapters X and XI, of the
connection between the changes occurring in radio-active products and
the radiations they emit. There is no doubt that the emanations, apart
from the excited activity to which they give rise, only give out α rays,
consisting most probably of positively charged bodies projected with
great velocity.
Effect of pressure on the rate of production of the Emanation.
=157.= It has already been mentioned that the conductivity due to the
thorium emanation is proportional to the pressure of the gas, pointing
to the conclusion that the rate of production of the emanation is
independent of the pressure, as well as of the nature of the surrounding
gas. This result was directly confirmed with the apparatus of Fig. 55.
When the pressure of the gas under the vessel was slowly reduced, the
radiation, tested outside the window, increased to a limit, and then
remained constant over a wide range of pressure. This increase, which
was far more marked in air than in hydrogen, is due to the fact that the
α rays from the emanation were partially absorbed in the gas inside the
vessel when at atmospheric pressure. At pressures of the order of 1
millimetre of mercury the external radiation decreased, but experiment
showed that this must be ascribed to a removal of the emanation by the
pump, and not to a change in the rate of production. The thorium
compounds very readily absorb water-vapour, which is slowly given off at
low pressures, and in consequence some of the emanation is carried out
of the vessel with the water-vapour.
Curie and Debierne[250] found that both the amount of excited activity
produced in a closed vessel containing active samples of radium, and
also the time taken to reach a maximum value, were independent of the
pressure and nature of the gas. This was true in the case of a solution
down to the pressure of the saturated vapour, and in the case of solid
salts to very low pressures. When the pump was kept going at pressures
of the order of ·001 mm. of mercury, the amount of excited activity was
much diminished. This was probably not due to any alteration of the rate
of escape of the emanation, but to the removal of the emanation by the
action of the pump as fast as it was formed.
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