It was soon observed that the thorium emanation passed unchanged through
acid solutions, and later the same result was shown to hold true in the
case of both emanations for every reagent that was tried. Preliminary
observations[251] showed that the thorium emanation, obtained in the
usual way by passing air over thoria, passed unchanged in amount through
a platinum tube heated electrically to the highest temperature
obtainable. The tube was then filled with platinum-black, and the
emanation passed through it in the cold, and with gradually increasing
temperatures, until the limit was reached. In another experiment, the
emanation was passed through a layer of red-hot lead-chromate in a glass
tube. The current of air was replaced by a current of hydrogen, and the
emanation was sent through red-hot magnesium-powder and red-hot
palladium-black, and, by using a current of carbon dioxide, through
red-hot zinc-dust. In every case the emanation passed through without
sensible change in the amount. If anything, a slight increase occurred,
owing to the time taken for the gas-current to pass through the tubes
when hot being slightly less than when cold, the decay _en route_ being
consequently less. The only known gases capable of passing in unchanged
amount through all the reagents employed are the recently discovered
members of the argon family.
But another possible interpretation might be put upon the results. If
the emanation were the manifestation of a type of excited radio-activity
on the surrounding atmosphere, then, since from the nature of the
experiments it was necessary to employ in each case as the atmosphere, a
gas not acted on by the reagent employed, the result obtained might be
expected. Red-hot magnesium would not retain an emanation consisting of
radio-active hydrogen, nor red-hot zinc-dust an emanation consisting of
radio-active carbon dioxide. The incorrectness of this explanation was
shown in the following way. Carbon dioxide was passed over thoria, then
through a =T=-tube, where a current of air met and mixed with it, both
passing on to the testing-cylinder. But between this and the =T=-tube a
large soda-lime tube was introduced, and the current of gas was thus
freed from its admixed carbon dioxide, before being tested in the
cylinder for the emanation. The amount of emanation found was quite
unchanged, whether carbon dioxide was sent over thoria in the manner
described, or whether, keeping the other arrangements as before, an
equally rapid current of air was substituted for it. The theory that the
emanation is an effect of the excited activity on the surrounding medium
is thus excluded.
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