The following table shows the results obtained for different currents of
hydrogen and oxygen.
Current of Gas _T₁_ _T₂_
Hydrogen ·25 c.c. per sec. −151·3 −150
„ ·32 „ „ −153·7 −151
„ ·92 „ „ −152 −151
„ 1·38 „ „ −154 −153
„ 2·3 „ „ −162·5 −162
Oxygen ·34 „ „ −152·5 −151·5
„ ·58 „ „ −155 −153
The temperature _T₁_ in the above table gives the temperature of initial
volatilization, _T₂_ the temperature for which half of the condensed
emanation had been released. For slow currents of hydrogen and oxygen,
the values of _T₁_ and _T₂_ are in good agreement. For a stream of gas
as rapid as 2·3 cubic centimetres per second the value of _T₁_ is much
lower. Such a result is to be expected; for, in too rapid a stream, the
gas is not cooled to the temperature of the spiral, and, in consequence,
the inside surface of the spiral is above the mean temperature, and some
of the emanation escapes at a temperature apparently much lower. In the
case of oxygen, this effect appears for a gas stream of 0·58 cubic
centimetres per second.
In the experiments on the thorium emanation, on account of the rapid
loss of activity, a slightly different method was necessary. The steady
stream of gas was passed over the thorium compound, and the temperature
was observed at the instant when an appreciable movement of the
electrometer appeared. This gave the temperature at which a small
fraction of the thorium emanation escaped condensation, and not the
value _T₁_ observed for the radium emanation, which gave the temperature
for which a small fraction of the previously condensed emanation was
volatilized.
The following table illustrates the results obtained.
Current of Gas Temperature
Hydrogen ·71 c.c. per −155° C.
sec.
„ 1·38 „ „ −159° C.
Oxygen ·58 „ „ −155° C.
On comparing these results with the values obtained for the radium
emanation, it will be observed that with equal gas streams the
temperatures are nearly the same.
A closer examination of the thorium emanation showed, however, that this
apparent agreement was only accidental, and that there was, in reality,
a very marked difference in the effect of temperature on the two
emanations. It was found experimentally that the radium emanation was
condensed very near the temperature at which volatilization commenced,
and that the points of condensation and volatilization were defined
fairly sharply.
[Illustration: Fig. 60.]
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