=176. Concentration of excited radio-activity on the negative
electrode.= When thorium or radium is placed in a closed vessel, the
whole interior surface becomes strongly active. In a strong electric
field, on the other hand, the writer found that the activity was
confined entirely to the negative electrode. By suitable arrangements,
the whole of the excited activity, which was previously distributed over
the surface of the vessel, can be concentrated on a small negative
electrode placed inside the vessel. An experimental arrangement for this
purpose is shown in Fig. 63.
[Illustration: Fig. 63.]
The metal vessel _V_ containing a large amount of thoria is connected
with the positive pole of a battery of about 300 volts. The wire _AB_ to
be made active is fastened to a stouter rod _BC_, passing through an
ebonite cork inside a short cylinder _D_, fixed in the side of the
vessel. This rod is connected with the negative pole of the battery. In
this way the wire _AB_ is the only conductor exposed in the field with a
negative charge, and it is found that the whole of the excited activity
is concentrated upon it.
In this way it is possible to make a short thin metal wire over 10,000
times as active per unit surface as the thoria from which the excited
activity is derived. In the same way, the excited activity due to radium
can be concentrated mainly on the negative electrode. In the case of
thorium, if the central wire be charged positively, it shows no
appreciable activity. With radium, however, a positively charged body
becomes slightly active. In most cases, the amount of activity produced
on the positive electrode is not more than 5% of the corresponding
amount when the body is negatively charged. For both thorium and radium,
the amount of excited activity on electrodes of the same size is
independent of their material.
All metals are made active to equal extents for equal times of exposure.
When no electric field is acting, the same amount of activity is
produced on insulators like mica and glass as on conductors of equal
dimensions.
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