There has been a tendency to attach undue importance to this apparent
discrepancy between theory and experiment. The difficulty is not so much
to offer a probable explanation of the results as to select from a
number of possible causes. While there can be little doubt that the main
factor in the disintegration of the atom consists in the expulsion of an
α particle carrying a positive charge, a complicated series of processes
probably occurs before the residue of the atom is carried to the
negative electrode. The experimental evidence suggests that one or more
negative electrons of slow velocity escape from the atom at the same
time as the particle. This is borne out by the recent discovery that the
particle expelled from radium, freed from the ordinary β rays, and also
from polonium, is accompanied by a number of slowly moving and
consequently easily absorbed electrons. If two negative electrons
escaped at the same time as the α particle, the residue would be left
with a positive charge and would be carried to the negative electrode.
There is also another experimental point which is of importance in this
connection. In the absence of an electric field, the carriers remain in
the gas for a considerable time and undergo their transformation _in
situ_. There is also some evidence (section 227) that, even in an
electric field, the carriers of the active deposit are not swept to the
electrode immediately after the break up of the emanation, but remain
some time in the gas before they gain a positive charge. It must be
remembered that the atoms of the active deposit do not exist as a gas
and by the process of diffusion would tend to collect together to form
aggregates. These aggregates would act as small metallic particles, and,
if they were electro-positive in regard to the gas, would gain a
positive charge from the gas.
There can be little doubt that the processes occurring between the break
up of the emanation and the deposit of the residue in the cathode in an
electric field are complicated, and further careful experiment is
required to elucidate the sequence of the phenomena.
Public-domain text, read in full here on John Shaqi.
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