=198.= CASE 2. _A primary source supplies the matter A at a constant
rate and the process has continued so long that the amount of the
products A, B, C, ... has reached a steady limiting value. The primary
source is then suddenly removed. It is required to find the amounts of
A, B, C, ... remaining at any subsequent time t._
In this case, the number _n₀_ of particles of _A_, deposited per second
from the source, is equal to the number of particles of _A_ which change
into _B_ per second, and of _B_ into _C_, and so on. This requires the
relation
_n₀_ = λ₁_P₀_ = λ₂_Q₀_ = λ₃_R₀_ (6),
where _P₀_, _Q₀_, _R₀_ are the maximum numbers of particles of the
matter _A_, _B_, and _C_ when a steady state is reached.
The values of _P_, _Q_, _R_ at any time _t_ after removal of the source
are given by equations of the same form as (3) and (5) for a short
exposure. Remembering the condition that initially
_P_ = _P₀_ = _n₀_/λ₁,
_Q_ = _Q₀_ = _n₀_/λ₂,
_R_ = _R₀_ = _n₀_/λ₃,
it can readily be shown that
$$ P = \frac {n₀} {λ_1} e^{–λ_1 t} $$ .... (7),
$$ Q = \frac {n₀} {λ_1 − λ_2} (\frac {λ_1}
{λ_2} e^{–λ_2 t} − e^{–λ_1 t}) $$ .... (8),
$$ R = n₀ (ae^{–λ_1 t} + be^{–λ_2 t} + ce^{–λ_3
t}) $$ .... (9),
where
$$ a = \frac {λ_2} {(λ_1 − λ_2) (λ_1 -
λ_3)} $$,
$$ b = \frac {–λ_1} {(λ_1 − λ_2) (λ_2 -
λ_3)} $$,
$$ c = \frac {λ_1 λ_2} {λ_3 (λ_1 − λ_3)
(λ_2 − λ_3)} $$ .
[Illustration: Fig. 73.]
The relative numbers of atoms of _P_, _Q_, _R_ existing at any time are
shown graphically in Fig. 73, curves _A_, _B_, _C_ respectively. The
number of atoms _R₀_ is taken as 100 for comparison, and the values of
λ₁, λ₂, λ₃ are taken corresponding to the 3, 21, and 28-minute changes
in the active deposit of radium. A comparison with Fig. 72 for a short
exposure brings out very clearly the variation in the relative amounts
of _P_, _Q_, _R_ in the two cases. Initially the amount of _R_ decreases
very slowly. This is a result of the fact that the supply of _C_ due to
the breaking up of _B_ at first, nearly compensates for the breaking up
of _C_. The values of _Q_ and _R_ after several hours decrease
exponentially, falling to half value in 28 minutes.
=199.= CASE 3. _Suppose that a primary source has supplied the matter A
at a constant rate for any time T and is then suddenly removed. Required
the amounts of A, B, C at any subsequent time._
Suppose that _n₀_ particles of the matter _A_ are deposited each second.
After a time of exposure _T_, the number of particles _P_{T}_ of the
matter _A_ present is given by
$$ P_T = n₀ \int₀^T e^{–λ_1 t} dt = \frac {n₀} {λ_1} (1 -
e^{–λ_1 T}) $$ .
At any time _t_, after removal of the source, the number of particles
_P_ of the matter _A_ is given by
$$ P = P_T e^{–λ_1 t} = \frac {n₀} {λ_1} (1 − e^{–λ_1
T}) e^{–λ_1 t} $$ .
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