The active deposit gave out α and β (and probably γ) rays. It was
difficult to decide definitely whether actinium X gave out β as well as
α rays. When the actinium X was heated to a red heat, the β activity was
temporarily reduced to about half its initial value. This decrease was
probably due to the removal of the active deposit, which, we have seen,
is readily volatilized by heat. If the β ray activity cannot be further
reduced, this would point to the conclusion that actinium X, as well as
actinium B, gives out β rays, but the evidence so far obtained is not
conclusive.
The ease with which the active deposit is volatilized by heat offers a
very simple explanation of the initial peculiarities of the decay and
recovery curves (Fig. 82) of actinium X. The activity of actinium X
rises at first, but there is no corresponding decrease in the activity
of the actinium left behind. It has been shown that the active deposit
is soluble in ammonia, and, in consequence, is removed with the actinium
X. The products actinium A and B and actinium X, immediately after
separation, are in radio-active equilibrium and we should not therefore
expect to find any increase of activity after removal, such as is
observed in the case of thorium, where thorium A and B are not removed
with thorium X. However, in heating the actinium X to drive off the
ammonium salts, some of the active deposit is volatilized. After
cooling, the amount of the active deposit increases to nearly its old
value and there is a corresponding increase of the activity.
[Illustration: Fig. 84.]
=214. Products of Actinium.= There is one very interesting point of
distinction between the radio-active behaviour of thorium and actinium.
The latter after removal of actinium X, shows only about 5 per cent. of
the original activity, while thorium, after removal of Th X, always
shows a residual activity of about 25 per cent. of the maximum value.
This very small residual activity indicates that actinium, if completely
freed from all its products, would not give out rays at all, in other
words, the first change in actinium is a rayless one.
The radio-active products of actinium are shown graphically in Fig. 84.
Some of their chemical and physical properties are tabulated below.
Products Time to be Rays Some Physical and
half Chemical properties
transformed
Actinium ? No rays Insoluble in ammonia
Actinium X 10·2 days α, (β and γ) Soluble in ammonia
Emanation 3·9 secs. α rays Behaves as a gas
Actinium A 35·7 mins. No rays Soluble in ammonia
and strong acids.
Actinium B 2·15 mins. α, β and γ Volatilized at
100°C. B can be
separated from A by
electrolysis
Footnote 296:
Public-domain text, read in full here on John Shaqi.
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