In the above calculations it is assumed, as a first approximation, that
the β rays from C and E have the same average velocity. This is probably
not accurately the case, but the above number certainly serves to fix
the order of magnitude of the period of the product D. This calculation
is confirmed by observations to be given later on the amount of D and E
in old radium.
It may be of interest to mention that the writer calculated the period
of radium F by a similar method, before its value was experimentally
determined, and found that F should be half transformed in about one
year. This is not very different from the experimental value of 143 days
found later. In addition, it was assumed in the calculation that the α
particles from C and F were projected with the same velocity, and in
consequence produced the same amount of ionization. In practice,
however, it is found that the α particle of F is absorbed in about half
the distance of the α particles of C, and in consequence produces only
about half of the ionization of the latter. If this correction were
made, the calculated period for half transformation would be six months
instead of one year.
A table of the transformation products of radium, together with some of
their physical and chemical properties, is given below.
Transformation Time to be Rays Chemical and
Products half Physical
transformed Properties
Radium 1200 years α rays —
Emanation 3·8 days α rays Chemically
inert gas;
condenses at
−150° C.
Radium A 3 mins. α rays Behaves as
(active deposit solid;
of rapid deposited on
change) the surface of
bodies;
concentrated on
cathode in
electric field.
Soluble in
strong acids;
volatile at a
white heat. B
is more
volatile than A
or C.
:: B (same) 21 mins. no rays Same
:: C (same) 28 mins. α, β, γ rays Same
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