=238. Variation of the activity of radium with time.= It has been shown
that the activity of freshly prepared radium increases at first with the
time and practically reaches a maximum value after an interval of about
one month. The results already considered show that there is a still
further slow increase of activity with the time. This is the case
whether the activity is measured by the α or β rays. It will be shown
later that radium is probably half transformed in about 1000 years. From
this it can readily be calculated that after a lapse of about 200 years
the amount of the products radium D, E and F will have reached a maximum
value. The same number of atoms of each of the products C and E will
then break up per second. If each atom of these products in
disintegrating throws off an equal number (probably one) of β particles,
the number of β particles thrown off per second will be twice as great
as from radium a few months old. The number will increase at first at
the rate of about 2 per cent. a year.
Similar considerations apply to the α ray activity. Since, however,
there are four other products of radium besides radium itself which
expel α particles, the number of α particles emitted per second from old
radium will not be more than 25 per cent. greater than the number from
radium a few months old. The activity measured by the α rays will thus
not increase more than 25 per cent., and probably still less, as the α
particles from radium F produce less ionization than the α particles
expelled from the other radium products. The activity of radium will
consequently rise to a maximum after 200 years and then slowly die away
with the time.
=239. Presence of these products in pitchblende.= The products radium D,
E and F must be present in pitchblende in amounts proportional to the
quantity of radium present, and should be capable of separation from the
mineral by suitable chemical methods. The radio-active properties of
these substances, if obtained in the pure state, are summarized below.
_Radium D_ when first separated, should give out very little α or β
radiation. The β ray activity will rapidly increase, reaching half its
maximum value in 6 days. The α ray activity will at first increase
nearly proportionately with the time, and will reach a maximum value
after an interval of about 3 years. The α and β ray activity, after
reaching a maximum, will finally decay, the activity falling to half
value in about 40 years. Since radium D is half transformed in 40 years,
and radium in 1200 years, the maximum β ray activity of radium D, weight
for weight, will be about 300 times that of radium.
The α ray activity, at any time, will be removed by placing a bismuth
disk in the solution.
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