emission from the 1 gram of radiferous barium, containing about ⅙ of
its weight of pure radium chloride, was 14 gram-calories per hour.
Measurements were also made with 0·08 gram of pure radium chloride.
Curie and Laborde deduced from these results that 1 gram of pure radium
emits a quantity of heat equal to about 100 gram-calories per hour. This
result was confirmed by the experiments of Runge and Precht[327] and
others. As far as observation has gone at present, this rate of emission
of heat is continuous and unchanged with lapse of time. Therefore, 1
gram of radium emits in the course of a day 2400, and in the course of a
year 876,000 gram-calories. The amount of heat evolved in the union of
hydrogen and oxygen to form 1 gram of water is 3900 gram-calories. It is
thus seen that 1 gram of radium emits _per day_ nearly as much energy as
is required to dissociate 1 gram of water.
In some later experiments using 0·7 gram of pure radium bromide, P.
Curie[328] found that the temperature of the radium indicated by a
mercury thermometer was 3° C. above that of the surrounding air. This
result was confirmed by Giesel, who obtained a difference of temperature
of 5° C. with 1 gram of radium bromide. The actual rise of temperature
observed will obviously depend upon the size and nature of the vessel
containing the radium.
During their visit to England in 1903 to lecture at the Royal
Institution, M. and Mme Curie performed some experiments with Professor
Dewar, to test by another method the rate of emission of heat from
radium at very low temperatures. This method depended on the measurement
of the amount of gas volatilized when a radium preparation was placed
inside a tube immersed in a liquefied gas at its boiling point. The
arrangement of the calorimeter is shown in Fig. 97.
[Illustration: Fig. 97.]
The small closed Dewar flask _A_ contains the radium in a glass tube
_R_, immersed in the liquid to be employed. The flask _A_ is surrounded
by another Dewar bulb _B_, containing the same liquid, so that no heat
is communicated to _A_ from the outside. The gas liberated in the tube
_A_ is collected in the usual way over water or mercury, and its volume
determined. By this method, the rate of heat emission of the radium was
found to be about the same in boiling carbon dioxide and oxygen, and
also in liquid hydrogen. Especial interest attaches to the result
obtained with liquid hydrogen, for at such a low temperature ordinary
chemical activity is suspended. The fact that the heat emission of
radium is unaltered over such a wide range of temperature indirectly
shows that the rate of expulsion of α particles from radium is
independent of temperature, for it will be shown later that the heating
effect observed is due to the bombardment of the radium by the α
particles.
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