Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
_________________________________________________________________________
| | | | |
| | F. Schulze | Lange | Cross and |
| Method | Dil. HNO_{3} | Fusion KOH | Bevan |
| | KClO_{3} | | Chlorine, &c. |
|_____________________________|______________|____________|_______________|
| | | | |
| Cellulose p.ct. obtained | 66.0 | 39.3-43.1 | 66.5 |
| Furfural p.ct. of cellulose | 7.0 | 3.96 | 5.62 |
| Residual nitrogen | 0.22 | 0.03 | 0.00 |
| Ferricyanide reaction, | | | |
| Prussian blue fixed | 6.04 | 0.89 | 0.92 |
|_____________________________|______________|____________|_______________|
The author remarks: 'It is evident no one feature can be urged as a
criterion in judging between the methods, but all must be taken into
consideration. Such a comparison shows the superiority of the
chlorination method.'
The cellulose is not of the normal (cotton) type, since on treatment
with sulphuric acid it dissolves with considerable discolouration, but
only to the extent of about 80 per cent. The dissolved monoses converted
into osazones were found to consist of hexoses only. The cellulose
treated with caustic soda solution (5 p.ct. NaOH) in the cold yielded 20
p.ct. of its weight of soluble constituents, but as the residue yielded
3.34 p.ct. furfural the attack of the alkali is by no means confined to
the furfuroids.
~Animal Digestion of the Constituents of Bran.~--Observations on a steer
fed upon wheat bran only established the following percentage digestion
of the several constituents:
Soluble carbohydrates 96.9
Starch 100.0
Free pentosanes 60.2
Cellulose 24.8
Lignin complex 36.7
Proteid 82.96
Ether extract 42.73
_____________________ ______
Nitrogen-free extract 76.08
Crude fibre 32.21
JOURNAL OF THE IMPERIAL INSTITUTE
(Research Department, Vols. 1-2, 1895-6).
(p. 109) In this journal appear a series of notices of the results of
analyses of vegetable fibres by the method described in 'Report on
Miscellaneous Fibres' (Col. Ind. Exhibition Reports, p. 368) [C. F.
Cross]. These investigations deal with the following subjects:
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