Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
_Estimation of Cellulose._--The author investigated the process of Lange
and the 'celluloses' obtained from various raw materials. The products
from the woods of birch and maple contained furfural-yielding
constituents, represented by yields of 6-8 p.ct. furfural. Preference is
given to the process by comparison with others, at the same time that it
is recommended in all cases to examine the product for furfural
quantitatively, converting the numbers into pentosane equivalents, and
subtracting from the total 'cellulose' to give the true cellulose.
ZUR KENNTNISS DER MUTTERSUBSTANZEN DES HOLZGUMMI.
E. WINTERSTEIN (Ztschr. Physiol. Chem., 1892, 381).
~ON THE MOTHER SUBSTANCES OF WOOD-GUM.~
(p. 188) According to the text-books beech-wood may be regarded as the
typical raw material for the preparation of the laboratory product known
as wood-gum. The author has subjected beech-wood and beech-wood
cellulose (Schulze process) to a range of hydrolytic treatments, acid
and alkaline, in order to determine the conditions of selective action
upon the mother substance of the wood-gum. In the main it appears that
this group of furfuroids is equally resistant with the cellulose
constituents of the wood; in fact, that the mother substance of wood-gum
is a modified cellulose, and exists in the wood in chemical combination
with the 'incrusting substances.'
Of the author's experimental results the following may be cited as
typical:
Yield of furfural
Substance p.ct.
Original beech-wood 13.8
After boiling 3 hrs. with 1.25 p.ct. H_{2}SO_{4} (residue) 10.1
" " " " 5.0 " " " 5.6
Cellulose--isolated by Schulze process (yield 53 p.ct.) 6.9
" after further 14 days' digestion with the
Schulze acid (HNO_{3} + KClO_{3}) 5.9
" after extraction with 5 p.ct. NaOH in
cold (residue) 5.0
" after second extraction with 5 p.ct. NaOH
in cold (residue) 4.4
UEBER DIE FRAGE NACH DEM URSPRUNG UNGESAeTTIGER VERBINDUNGEN IN DER
PFLANZE.
C. F. CROSS, E. J. BEVAN, and C. SMITH (Berl. Ber., 1895, 1940).
~ON THE SOURCE OF THE UNSATURATED COMPOUNDS OF THE PLANT.~
Public-domain text, read in full here on John Shaqi.
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