Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
(p. 224) A group of constituents of many seeds, distinguished by giving
slimy or ropy 'solutions' under the action of boiling water are
designated 'amyloid.' They are reserve materials, and in this, as in the
physical properties of their 'solutions,' they are very similar to
starch. They are, however, not affected by diastase; and generally are
more resistant to hydrolysis. Typical amyloids have been isolated by the
author from seeds of _Tropoeolum majus, Poeonia officinalis_, and
_Impatiens Balsamina_. The raw material was carefully purified by
exhaustive treatment with ether and alcohol, &c.; the amyloid then
extracted by boiling with water, and isolated by precipitation with
alcohol. Elementary analysis gave the numbers C 43.2, H 6.1. On boiling
with 12 p.ct. HCl it gave 15.3 p.ct. furfural; oxidised with nitric acid
it yielded 10.4 p.ct. mucic acid. Specimens from the two first-named raw
materials gave almost identical numbers.
_Hydrolysis._--On boiling with dilute acids these products are gradually
broken down, dissolving without residue. In this respect they are
differentiated from the mucilages, which give a residue of cellulose
(insoluble). From the solution the author isolated crystalline
galactose, but failed to isolate a pentose. Dextrose was also not
identified directly.
The tissue residues left after extracting the amyloid constituent, as
above described, were subjected to acid hydrolysis. A complex of
products was obtained, from which galactose was isolated. A
furfural-yielding carbohydrate was also present in some quantity, but
could not be isolated. The original seed tissues, therefore, contain an
amyloid and a hemicellulose, the latter differentiated in its resistance
to water. Both yield, however, to acid hydrolysis a complex of products
of similar composition and constitution.
UEBER DEN GEHALT DES TORFES AN PENTOSANEN ODER FURFUROLGEBENDEN STOFFEN
UND AN ANDEREN KOHLENHYDRATEN.
H. V. FEILITZEN and B. TOLLENS (Berl. Ber., 1897, 2,571).
~CARBOHYDRATE CONSTITUENTS OF PEAT.~
(p. 240) An investigation of typical peats taken at successive depths
showed increasing percentage of carbon, and inversely a decreasing yield
of furfural. The numbers may be compared with those for _Sphagnum
cuspidatum_--with C = 49.80 p.ct., and furfural 7.99 p.ct., calculated
to dry, ash-free substance:
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