Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
It is clear that the aqueous solutions of cellulose have a double
advantage in this respect--not only do they readily yield an
approximately pure cellulose as a direct product of regeneration or
decomposition, but the first cost of the solution is very much less.
With these newer products, therefore, the spinning problem enters on a
new phase of struggle. It is certain that at selling prices at or about
5s. to 7s., very large markets will be open to the product or
products. The two processes which are or may be able to fulfil this
demand are those based (1) on cuprammonium solutions of cellulose, (2)
on the sulphocarbonate or viscose. As regards _first cost_ of the
solution the latter has a large advantage. One ton of wood pulp (at
12l.) can certainly be obtained in solution in a condition ready for
spinning at a total cost (materials) of less than 30l. The
cuprammonium process, so far as 'outside' information goes, requires for
production of the solution (1) cotton as raw material, (2) ammonia
(calc. as concentrated aqueous) equal to 1-1/2 times its weight, and
(3) metallic copper 25 p.ct. of its weight; and the costs are
approximately 100l. per ton. It is obvious that the materials are
recoverable from the precipitating-bath, but at a certain added cost. We
have no statements as to the proportion recoverable nor the costs
incurred, and we are therefore unable to measure the total net cost of
the regenerated cellulose by this process. It is certainly much less
than by the collodion processes. As to the textile quality of the
thread, the product has not yet been on a sufficiently wide selling
basis for that to have been determined. There are a great many factors
which enter here. Not merely the external characters of lustre,
softness, and translucency, but the all-important quality of uniformity
of thread. The collodion-spinning is a process still very defective in
this respect, and the defect is no doubt referable to the difficulty of
securing absolute physical invariability of the collodion. It is to be
regretted, in the interests of scientific development, that none of the
technologists who have published investigations of these processes have
entered into the discussion of the fundamental factors of the spinning
processes; we are, therefore, unable at this stage to discuss these
elements of a full comparison in greater detail. We cannot, for this
reason, say how far the cuprammonium process diverges in point of
control from the standard of the collodion processes. Of the 'viscose'
product we have a more intimate knowledge, and it certainly reaches a
higher general standard than the older and now well-known artificial
silks. The process is also sufficiently developed to enable the total
costs of production to be estimated at a figure less than one-half that
of the 'collodion' processes. This would assure to this system an
_entree_ in this country, and a basis of expansion limited only by the
ordinary laws of supply and demand.
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