Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
Digested with caustic soda solution it yielded 33 p.ct. of its weight of
the soluble 'acid cellulose.' This product was purified and analysed
with the following result: C 43.35 H 6.5. For the direct production of
the 'acid' derivative, cellulose was boiled with successive quantities
of 30 p.ct. NaOH until _dissolved_. It required eight treatments of one
hour's duration. On adding sulphuric acid to the solutions the product
was precipitated. Yield 40 p.ct. Analyses:
C 43.8 43.8 43.7
H 6.2 6.2 6.3
The cellulose reprecipitated from solution in Schweizer's reagent gave
similar analytical results:
C 43.9 43.8 44.0
H 6.5 6.3 6.4
_Conversion into nitrates._--The original cellulose, hydral- and acid
cellulose were each treated with 10 times their weight of HNO_{3} of
1.48 sp.gr. and heated at 85 deg. until the solution lost its initial
viscosity.
The products were precipitated by water and purified by solution in
acetone from which two fractions were recovered, the one being
relatively insoluble in ethyl alcohol. The various nitrates from the
several original products proved to be of almost identical composition,
C 32.0 H 4.2 N 8.8
with a molecular weight approximately 1350. The conclusion is that
these products are all derivatives of a 'hydralcellulose'
6C_{6}H_{10}O_{5}H_{2}O.
FORMATION OF FURFURALDEHYDE FROM CELLULOSE, OXYCELLULOSE, AND
HYDROCELLULOSE.
By LEO VIGNON (Compt. rend., 1898, 126, 1355-1358).
Public-domain text, read in full here on John Shaqi.
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