Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
(p. 54) Hydrocellulose, oxycellulose, and 'reduced' cellulose, the last
named being apparently identical with hydrocellulose, were obtained by
heating carefully purified cotton wool (10 grams) in water (1,000 c.c.),
with (1) 65 c.c. of hydrochloric acid (1.2 sp.gr.), (2) 65 c.c. of
hydrochloric acid and 80 grams of potassium chlorate, (3) 65 c.c. of
hydrochloric acid and 50 grams of stannous chloride. From these and some
other substances, the following percentage yields of furfuraldehyde were
obtained: Hydrocellulose, 0.854; oxycellulose, 2.113; reduced cellulose,
0.860; starch, 0.800; bleached cotton, 1.800; oxycellulose, prepared by
means of chromic acid, 3.500. Two specimens of oxycellulose were
prepared by treating cotton wool with hydrochloric acid and potassium
chlorate (A), and with sulphuric acid and potassium dichromate (B), and
25 grams of each product digested with aqueous potash. Of the product A,
16.20 grams were insoluble in potash, 2.45 grams were precipitated on
neutralisation of the alkaline solution, and 6.35 grams remained in
solution, whilst B yielded 11.16 grams of insoluble matter, 1.42 grams
were precipitated by acid, and 12.42 grams remained in solution. The
percentage yields of furfuraldehyde obtained from these fractions were
as follows: A, insoluble, 0.86; precipitated, 4.35; dissolved, 1.10. B,
insoluble, 0.76; precipitated, 5.11; dissolved, 1.54. It appears, from
the foregoing results, that the cellulose molecule, after oxidation, is
easily decomposed by potash, the insoluble and larger portion having all
the characters of the original cellulose, whilst the soluble portion is
of an aldehydic nature, and contains a substance, precipitable by acids,
which yields a relatively large amount of furfuraldehyde.
UNTERSUCHUNGEN UeBER DIE OXYCELLULOSE.
O. V. FABER und B. TOLLENS (Berl. Ber., 1899, 2589).
~Investigations of Oxycellulose.~
(p. 61) The author's results are tersely summed up in the following
conclusions set forth at the end of the paper: The oxycelluloses are
mixtures of cellulose and a derivative oxidised compound which contains
one more atom O than cellulose (cellulose = C_{6}H_{10}O_{5}), and for
which the special designation _Celloxin_ is proposed.
Celloxin may be formulated C_{8}H_{6}O_{6} or C_{6}H_{10}O_{6}, of which
the former is the more probable.
The various oxycelluloses may be regarded as containing one celloxin
group to 1-4 cellulose groups, according to the nature of the original
cellulose, and the degree of oxidation to which subjected. These groups
are in chemical union.
Celloxin has not been isolated. On boiling the oxycelluloses with
lime-milk it is converted into isosaccharinic and dioxybutyric acids.
The insoluble residue from the treatment is cellulose.
The following oxycelluloses were investigated:
A. _Product of action of nitric acid upon pine wood_ (Lindsey and
Tollens, Ann. 267, 366).--The oxycelluloses contained
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