Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
(p. 84) Straw cellulose is resolved by two methods of acid hydrolysis
into a soluble furfural-yielding fraction, and an insoluble fraction
closely resembling the normal cellulose. (a) The cellulose is
dissolved in sulphuric acids of concentration, H_{2}SO_{4}.2H_{2}O,
H_{2}SO_{4}.3H_{2}O. As soon as solution is complete, the acid is
diluted. A precipitate of cellulose hydrate (60-70 p.ct.) is obtained,
and the filtered solution contains 90-95 p.ct. of the furfuroids of the
original cellulose. The process is difficult to control, however, in
mass, and to obtain the latter in larger quantity the cellulose (b) is
digested with six times its weight of 1 p.ct. H_{2}SO_{4} at 3 atm.
pressure, the products of the action being (1) a disintegrated cellulose
retaining only a small fraction (1/12) of the furfural-yielding groups,
and (2) a slightly coloured solution of the hydrolised furfuroids. An
investigation of the latter gave the following results: By oxidation
with nitric acid no saccharic acid was obtained; showing the absence of
dextrose. The numbers for cupric reduction were in excess of those
obtained with the hexoses. The yield of ozazone was high, viz. 30 to 40
p.ct. of the weight of the carbohydrate in solution. On fractionating,
the melting-points of the fractions were found to lie between 146 deg. and
153 deg.. Ultimate analysis gave numbers for C, H, and N identical with
those of a pentosazone. The product of hydrolysis appears, therefore, to
be xylose or a closely related derivative.
All attempts to obtain a crystallisation of xylose from the solution
neutralised (BaCO_{3}), filtered, and evaporated, failed. The reaction
with phloroglucol and HCl, moreover, was not the characteristic red of
the pentoses, but a deep violet. The product was then isolated as a dry
residue by evaporating further and drying at 105 deg.. Elementary analysis
gave the numbers C 44.2, 44.5, and H 6.7, 6.3. Determinations of
furfural gave 39.5 to 42.5 p.ct. On treating the original solution with
hydrogen peroxide, and warming, oxidation set in, with evolution of
CO_{2}. This was estimated (by absorption), giving numbers for CO_{2},
19.5, 20.5, 20.1 p.ct. of the substance.
The sum of these quantitative data is inconsistent with a pentose or
pentosane formula; it is more satisfactorily expressed by the empirical
formula
O
/ \
C_{5}H_{8}O_{3} CH_{2},
\ /
O
which represents a pentose monoformal. Attempts to synthesise a compound
of this formula have been so far without success.
UEBER EINIGE CHEMISCHE VORGAeNGE IN DER GERSTENPFLANZE.
C. F. CROSS, E. J. BEVAN, and C. SMITH (Berl. Ber., 1895, 2604).
~THE CHEMICAL LIFE-HISTORY OF THE BARLEY PLANT.~
Public-domain text, read in full here on John Shaqi.
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