Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
Generally we may sum up the present solution of the problem of the
relationship of the furfuroids to plant assimilation and growth as
follows:--The pentoses are not produced as such in the process of
assimilation; but furfural-yielding carbohydrates are produced directly
and in approximately constant ratio to the total carbohydrates; they are
mainly located in the permanent tissue; in the secondary changes of
dehydration, &c., accompanying maturation they undergo such
differentiation that they become readily separable by processes of acid
hydrolysis from the more resistant normal celluloses; but in relation to
alkaline treatments they maintain their intimate union with the latter.
They are finally converted into pentoses by artificial treatments, and
into pentosanes in the plant, with loss of 1 C atom in an oxidised form.
The mechanism of this transformation of hexoses into pentoses is not
cleared up. It is independent of external conditions, e.g.
fertilisation and atmospheric oxidations, and is probably therefore a
process of internal rearrangement of the character of an oxidation.
ZUR KENNTNISS DER IN DEN MEMBRANEN DER PILZE ENTHALTENEN BESTANDTHEILE.
E. WINTERSTEIN (Ztschr. Physiol. Chem., 1894, 521; 1895, 134).
~ON THE CONSTITUENTS OF THE TISSUE OF FUNGI.~
(p. 87) These two communications are a contribution of fundamental
importance, and may be regarded as placing the question of the
composition of the celluloses of these lowest types on a basis of
well-defined fact. In the first place the author gives an exhaustive
bibliography, beginning with the researches of Braconnot (1811), who
regarded the cellular tissue of these organisms as a specialised
substance, which he termed 'fungin.' Payen rejects this view, and
regards the tissue, fully purified by the action of solvents, as a
cellulose (C_{6}H_{10}O_{5}). This view is successively supported by
Fromberg [Mulder, Allg. Phys. Chem., Braunschweig, 1851], Schlossberger
and Doepping [Annalen, 52, 106], and Kaiser. De Bary, on a review of the
evidence, adopts this view, but, as the purified substance fails to give
the characteristic colour-reactions with iodine, he uses the qualifying
term 'pilzcellulose' [Morph. u. Biol. d. Pilze u. Flechten, Leipzig,
1884].
C. Richter, on the other hand, shows that these reactions are merely a
question of methods of purification or preparation [Sitzungsber. Acad.
Wien, 82, 1, 494], and considers that the tissue-substance is an
ordinary cellulose, with the ordinary reactions masked by the presence
of impurities. In regard to the lower types of fungoid growth, such as
yeast, the results of investigators are more at variance. The researches
of Salkowski (p. 113) leave little doubt, however, that the
cell-membrane is of the cellulosic type.
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