Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
_____________________________________________________________
| | | | |
| | Original seed | Malt or | Pentosane in |
| | | germinated product | |
| | | |_______________|
| | | | | |
| | A | B | A | B |
|________|_______________|____________________|_______|_______|
| | | | | |
| Barley | 500.00 | 434.88 | 39.58 | 40.38 |
| " | 500.00 | 442.26 | 40.52 | 41.17 |
| Peas | 300.00 | 286.60 | 15.25 | 15.97 |
|________|_______________|____________________|_______|_______|
The authors conclude generally that there is a slight absolute increase
in the pentosanes, and that the pentosanes do not belong to those
reserve materials which undergo destructive oxidation during
germination.
In this they confirm the previously published results of De Chalmot,
Cross and Bevan, and Gotze and Pfeiffer.
UEBER DEN GEHALT DER BAUMWOLLE AN PENTOSAN.
H. SURINGAR and B. TOLLENS (Ztschr. angew. Chem., 1897, I).
~PENTOSANE CONSTITUENTS OF COTTON.~
(p. 290) It has been stated by Link and Voswinkel (Pharm. Centralhalle,
1893, 253), that raw cotton yields 'wood gum' as a product of
hydrolysis. The authors were unable to obtain any pentoses as products
of acid hydrolysis of raw cotton, and traces only of furfural-yielding
carbohydrates. They conclude that raw cotton contains no appreciable
quantity of pentosane.
FOOTNOTES:
[8] This paper appears during the printing of the author's original MS.
[9] This paper appears during the printing of the author's original MS.
SECTION VI. THE LIGNOCELLULOSES
(p. 131) ~Lignocellulose Esters.~--By a fuller study of the ester
reactions of the normal celluloses we have been able to throw some light
on the constitutional problems involved; and we have extended the
investigations to the jute fibre as a type of the lignocelluloses, from
the results of which we get a clearer idea of the relationships of the
constituent groups.
Taking the empirical expression for the complex, i.e. the entire
lignocellulose, the formula C_{12}H_{18}O_{9}, we shall be able to
compare the ester derivatives with those of the celluloses, which we
have also referred to a C_{12} unit. But we shall require also to deal
with the constituent groups of the complex, which for the purposes of
this discussion may be regarded as (a) a cellulose of normal
characteristics--cellulose alpha; (b) a cellulose yielding furfural on
boiling with condensing acids--cellulose beta; and (c) a much
condensed, and in part benzenoid, group which we may continue to term
the lig_none_ group.
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