From a series of careful measurements and special tests the following
apparent volumes for different parts of the system have been calculated:
Liters.
Volume of the chair calorimeter chamber (without fixtures) 1360.0
Permanent fixtures (5); chair and supports (8) 13.0
------
Apparent volume of air inside chamber 1347.0
Air in pipes, blower, and valves to surface of acid in
first acid vessel 4.5
------
Apparent volume of air containing water-vapor 1351.5
Air above surface of acid in first sulphuric-acid vessel and
potash-lime can 16.0
------
Apparent volume of air containing carbon dioxide 1367.5
Air in potash-lime can, second sulphuric-acid vessel and connections,
sodium-bicarbonate cans, and pipes to calorimeter chamber 23.5
------
Apparent volume of air containing carbon dioxide, water, oxygen,
and nitrogen 1391.0
These volumes represent conditions existing inside the chamber without
the subject, _i. e._, conditions under which an alcohol check-test would
be conducted. In an experiment with man it would be necessary to deduct
the volume of the man, books, urine bottles, and all supplemental
apparatus and accessories. Under these circumstances the apparent volume
of the air in the chamber may at times be diminished by nearly 90 to 100
liters. At the beginning of each experiment the apparent volume of air
is calculated.
RESIDUAL ANALYSES.
CALCULATION FROM RESIDUAL ANALYSES.
The increment in weight of the absorbers for water and carbon dioxide
and the loss in weight of the oxygen cylinder give only an approximate
idea of the amounts of carbon dioxide and water-vapor produced and
oxygen absorbed during the period, and it is necessary to make
correction for change in the composition of the air as shown by the
residual analyses and for fluctuations in the actual volume. In order to
compute from the analyses the total carbon-dioxide content of the
residual air, it is necessary to know the relation of the air used for
the sample to the total volume, and thus we must know accurately the
volume of air passing through the gas-meter.
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