Any variations in the residual amount of carbon dioxide or water-vapor
likewise affect the oxygen. Thus, if there is an increase of 1 gram in
the amount of residual carbon dioxide, this corresponds to 0.51 liter,
and consequently an equal volume of oxygen is not admitted to the
chamber during the period, since its place has been taken by the
increased volume of carbon dioxide. A similar reasoning will show that
increase in the water-vapor content will have a similar effect, for each
gram of water-vapor corresponds to 1.25 liters and therefore influences
markedly the introduction of oxygen. All four of the factors, therefore
(barometric pressure, temperature, residual carbon dioxide, and residual
water-vapor), affect noticeably the oxygen determination.
CONTROL OF RESIDUAL ANALYSES.
Of the three factors to be determined in the residual air, the oxygen
(which is most important from the standpoint of the relative weight to
be placed upon the analysis) unfortunately can not be directly
determined without great difficulty. Furthermore, any errors in the
analysis may be very greatly multiplied by the known errors involved in
the determination of the true volume of the air in the chamber as a
result of the difficulties in obtaining the average temperature of the
air. Believing that the method of analysis as outlined above should be
controlled as far as possible by other independent methods, we were able
to compare the carbon dioxide as determined by the soda-lime method with
that obtained by the extremely accurate method used by Sondén and
Pettersson. An apparatus for the determination of carbon dioxide and
oxygen on the Pettersson principle has been devised by Sondén and
constructed for us by Grave, of Stockholm.
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