Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
This expansion amounts to 1/7692 part of the whole bulk of the water,
or 100,000 parts become 100,013. So far the amount of expansion is
very small, but this is only a foretaste of what is coming. Lower the
temperature still further, the water begins to freeze, and at the
moment of freezing it expands suddenly to an extent equalling 1/15 of
its bulk, _i.e._, of the bulk of so much water as becomes solidified.
The temperature remains at 32° until the whole of the water is frozen.
Fortunately for us, the freezing of water is always a slow process,
for if this conversion of every 15 gallons into 16 took place
suddenly, all our pipes would rip open with something like explosive
violence. But such sudden freezing of any considerable quantity of
water is practically impossible, on account of the “latent heat” of
liquid water, which amounts to 142½°. All this is given out in the
act of freezing. It is this giving out of so much heat that keeps the
temperature of freezing water always at 32°, even though the air around
may be much colder. No part of the water can fall below 32° without
becoming solid, and that portion which solidifies gives out enough heat
to raise 142½ times its own quantity from 31° to 32°.
The slowness of thawing is due to the same general fact. An instructive
experiment may be made by simply filling a saucepan with snow or broken
ice, and placing it over a common fire. The slowness of the thawing
will surprise most people who have not previously tried the experiment.
It takes about as long to melt this snow as it would to raise an equal
weight of water from 32° to 174°. Or, if a pound of water at 174° be
mixed with a pound of snow at 32°, the result will be two pounds of
water at 32°; 142° will have disappeared without making the snow any
warmer, it will all have been used up in doing the work of melting.
The force with which the great expansion due to freezing takes place is
practically irresistible. Strong pieces of ordnance have been filled
with water, and plugged at muzzle and touch-hole. They have burst in
spite of their great thickness and tenacity. Such being the case, it
is at first sight a matter of surprise that frozen water-pipes, whether
of lead or iron, ever stand at all. They would not stand but for
another property of ice, which is but very little understood, viz., its
_viscosity_.
Public-domain text, read in full here on John Shaqi.
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