Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
There is, however, one case in which a fire _appears_ to thus consume
its own smoke, but the appearance is delusive. I refer to fires lighted
from above. These, if properly managed, are practically smokeless,
and it is commonly supposed that smoke passes from the raw coal below
through the burning coal above, and is thereby consumed. The fact
is, however, that no such smoke is formed. That which under these
conditions comes from the coal beneath, when gradually heated by the
fire above, is combustible _gas_, and this gas is burned as it passes
through the fire. In this case the formation or non-formation of
smoke depends mainly on how this gas is burned, whether completely or
incompletely. If the air supplied for its combustion is insufficient,
smoke will be formed as it is when we turn up an Argand gas-flame so
high that the gas is too great in proportion to the quantity of air
that can enter the glass chimney.
Herein lies the fundamental principle. We may _prevent_ smoke, though
we cannot _cure_ it, and this prevention depends upon how we supply
air to the gas which the coal gives off when heated, and upon the
condition of this gas when we bring it in contact with the air by which
its combustion is to be effected. We must always remember that coal
when its temperature is sufficiently heated, whether in a gas retort
or fireplace, gives off a series of combustible hydrocarbon gases and
vapors, and all we have to do in order to obtain smokeless fires is to
secure the complete combustion of these.
Now we know that to burn a given quantity of gas we must supply it
with a sufficient quantity of oxygen, _i.e._, of the active principle
of the air; but this is not all: we all know well enough that if cold
coal-gas and cold air be brought together in any proportion whatever
no combustion occurs. A certain amount of heat is necessary to start
the chemical combination of oxygen with hydrogen and carbon, which
combination is the combustion, or burning.
Therefore, when the coal gas and the air are brought together one or
the other, or both, must be heated up to a certain point in order
that the combustion be complete. If cold there is no combustion; if
insufficiently heated, there is imperfect combustion, however well the
supplies may be regulated.
A very simple experiment that anybody may make illustrates this. When
an ordinary open fire is burning brightly and clearly without flame,
throw a few small pieces of raw coal into the midst of the glowing
coals. They will flame fiercely, but without smoking. Then throw a heap
of coal or one large lump on a similar fire. Now you will have dense
volumes of smoke, and little or no flame, simply because the cooling
action of the large bulk of coal in the course of distillation brings
the temperature of its gases below that required for their complete
combustion.
Public-domain text, read in full here on John Shaqi.
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