Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
Until quite lately it was customary to divide gases into two
classes—“permanent gases” and “condensable gases,” or “vapors.”
Gaseous water or steam was usually described as typical of the latter;
oxygen, hydrogen, or nitrogen of the former. Earlier than this, many
other gases were included in the permanent list; but Faraday made a
serious inroad upon this classification when he liquefied chlorine
by cooling and compressing it. Long after this, the gaseous elements
of water, and the chief constituents of air, oxygen, hydrogen, and
nitrogen, resisted all efforts to condense them; but now they have
succumbed to great pressure and extreme cooling.
We thus arrive at a very broad generalization, viz., that all gases are
physically similar to steam (I mean, of course, “dry steam,” _i.e._,
true invisible steam, and not the cloudy matter to which the name of
steam is popularly given), that they are all formed by raising liquids
above their boiling point, just as steam is formed when we boil water
and maintain the steam above the boiling-point of the water.
But some liquids boil at temperatures far below that at which others
freeze; liquid chlorine boils at a temperature below that of freezing
water, and liquid carbonic acid below even that of freezing mercury,
and liquid hydrogen far lower still. These are cases of boiling,
nevertheless, though it seems a paradox according to the ideas we
commonly attach to this word. But such ideas are based on our common
experience of the properties of our commonest of liquids, viz., water.
When water boils under the conditions of our ordinary experience, the
passage from the liquid to the gaseous state is a sudden leap, with
no intermediate state of existence that we are able to perceive; and
the conditions upon which water is converted into steam—the liquid
into the gas—while both are at the bottom of our atmospheric ocean,
are such as to render an intermediate condition rationally, as well as
practically, impossible.
We find that the expansive energy by which the steam is enabled to
resist atmospheric pressure is conferred upon it by its taking into
itself, and utilizing for its expansive efforts a large amount of
calorific energy. When any given quantity of water is converted into
steam, under ordinary circumstances, its bulk _suddenly_ becomes
above 1700 times greater—a cubic inch of water forms about a cubic
foot of steam, and nearly 1000 degrees of heat (966·6) disappears
_as temperature_. Otherwise stated, we must give to the cubic inch
of water at 212° as much heat as would raise it to a temperature of
212 plus 966·6, or 1,178·6°, if it remained liquid. This is about
the temperature of the glowing coals of a common fire; but the steam
that has thus taken enough heat to make the water red-hot is still at
212°—no _hotter_ than the water was while boiling.
Public-domain text, read in full here on John Shaqi.
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