Scientific American Supplement, No. 1082, September 26, 1896Various
Science
Scientific American Supplement, No. 1082, September 26, 1896
Various
Science -- Periodicals
The chemical composition, though of great general importance in
mineralogy, is of little practical value in the discrimination of
precious stones, since it is usually impossible to sacrifice a
sufficient quantity for chemical analysis. If we are dealing with a
faceted stone, not even the smallest portion can be utilized, for fear
of injuring it.
There is, however, one remarkable optical property, which is
ultimately related to the chemical composition. As is well known, many
substances possess the property of absorbing certain rays of light.
When the solar spectrum produced by admitting ordinary daylight
through a slit, and transmitting it through a prism, is passed through
the glowing vapor of certain substances, particular rays of light are
absorbed, and their absence from the emerging fight is manifested by
corresponding dark bands in the spectrum. The instrument by which the
observations are made is the spectroscope. It is well known to most
people that the solar spectrum itself contains certain dark bands of
this sort, which are produced by vapors that can be identified by the
position of the bands in the spectrum; and thus it is possible to
ascertain something regarding the chemical constitution of the sun and
certain of the heavenly bodies. Now, a precisely similar effect is
produced by certain elements if present in a mineral, by merely
transmitting the light through a piece of it. Thus, transparent
minerals which contain the rare element didymium betray the presence
of that element as soon as they are viewed through a spectroscope by
ordinary daylight; the spectrum is seen to be traversed by black bands
in the green, which are quite characteristic.
Among gem stones there are two which possess this curious property.
One is the variety of red garnet known as almandine, and the other is
the jargoon. The almandine produces characteristic bands in the green
and the jargoon in the red, green and blue portion of the spectrum. To
see these remarkable absorption spectra, to which attention was first
called, I think, by my friend, Prof. Church, it is not necessary to
look through the stone, it is quite sufficient to place it in a strong
light, and look at it through an ordinary pocket spectroscope; the
light which enters the instrument consists largely of rays which have
penetrated the stone, and been reflected from the facets at the back.
These rays produce the absorption spectrum. In this way we are enabled
to identify a jargoon or an almandine merely by looking at it. There
is no test so simple or so easy of application. It is curious that the
almandine, or iron aluminum garnet, is the only garnet which presents
an absorptive spectrum, and it is not yet certain to what element the
bands are due. In the case of jargoon, they are supposed to be caused
by the presence of some uranium compound in the mineral. All the
almandine garnets which I have examined, and nearly all the jargoons,
show these characteristic absorption spectra.
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