Scientific American Supplement, No. 299, September 24, 1881 — John Shaqi
Scientific American Supplement, No. 299, September 24, 1881Various
Science
Scientific American Supplement, No. 299, September 24, 1881
Various
Science -- Periodicals
These vapors, purified by ebullition at a low temperature, rise into a
second rectifying column, G, which terminates in the refrigerator, H,
filled with liquid sulphurous anhydride. This refrigerator is like those
which we employ in our sulphurous anhydride frigorific apparatus. Under
the action of a special pump, M, this liquid produces and maintains a
constant temperature of -25° to -30° in the refrigerator. The vapors of
alcohol condense therein at this low temperature, and the cold liquid
alcohol flows into the lower part of the refrigerator.
By the action of a return cock, a portion of this liquid falls upon
the plates of the column, G, and descends, while the vapors are rising
therein. The other portion of the liquid obtained flows into the
reservoir, K, at the beginning of the operation, and into the reservoir,
L, during all the remainder of the rectification. The ice-making machine
keeps up of itself alone the two operations.
In fact, the exhaust of the steam engine which actuates the sulphurous
anhydride pump is directed into a worm which circulates through the
first boiler, A, and the refrigerator, H, of the frigorific machine
keeps up the second rectification, which was brought about below the
surrounding temperature, and which for this reason takes place without
necessitating any combustion of coal. It suffices to cause the current
of water which issues from the condenser of the frigorific machine to
pass into the worm of the boiler.
We have, then, two results, two like operations, both produced by
the working of a single machine. Moreover, these two operations are
performed _in vacuo_, and we know that under these conditions they are
effected at lower temperatures. Owing to this fact, likewise, the weight
of the water that must be evaporated diminishes just so much. Now, one
kilogramme of water requires 636 heat units to cause it to pass from the
liquid to the gaseous state, while one kilogramme of alcohol requires
only 230 heat units to vaporize it. Thus every decrease of temperature
in rectification has for an immediate corollary an important economy of
fuel, which is proved by the diminution of radiation, and by the less
quantity of water to be distilled.
Between the boilers, A, in which is maintained a temperature bordering
on +50° to +60°, and the refrigerator, H, in which is easily obtained
a temperature of -30° to -40°, there is at our disposal a range of
temperature of nearly 100°, an immense difference compared with that
which can be made use of in ordinary apparatus. Thanks to this powerful
factor, which is manageable at will, we can take directly from the
apparatus alcohols marking 98 and 99 degrees by the centigrade
alcoholmeter. Such results are unobtainable by the usual methods.
We have likewise ascertained that at low temperatures the ebullition of
alcohol is as active as at near 100°.
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