Scientific American Supplement, No. 299, September 24, 1881Various
Science
Scientific American Supplement, No. 299, September 24, 1881
Various
Science -- Periodicals
Animal or vegetable oils or fats are composed of fatty acids in
combination with glycerine, and these, under the influence of
high-pressure steam, are decomposed or dissociated, the fatty acids
being liberated from the glycerine, leaving the former to act upon or
corrode the iron of the cylinder. But here their objectionable influence
does not end. They form with the iron hard, insoluble compounds called
iron soaps, which increase the friction between the cylinder and piston,
and in some cases gradually collect into the form of hard balls inside
the cylinder.
When the water is used over and over again a considerable proportion of
the fatty acids of the oils used for lubricating the piston is carried
over with the steam and is found in the condensed water which is
introduced into the boiler along with the water. Here it commences
action, which proves quite as injurious to the boiler as it does to the
cylinder, but in a different way. It acts upon the iron of the boiler
and on some of the lime salts which constitute the incrustation, forming
greasy iron and lime soaps, which prevent the water from coming into
absolute contact with it. Thus the heat cannot be drawn away quickly
enough by the water, and the plates thus coated above the flues are
liable to become burdened and weakened. This action has in many cases
gone on to such an extent that the flues have collapsed under the
pressure of the steam inside.
The authors give two different processes for the determination of animal
or vegetable oils or fats and hydrocarbon or other neutral oils. They
take a certain weight of the sample and boil it with twice its weight
of an eight per cent, solution of caustic soda in alcohol. The soda
combines with the fatty acids of the animal or vegetable oils forming
soaps; bicarbonate of soda is then added to neutralize the excess of
caustic soda; and, lastly, sand; and the whole is evaporated to dryness
at the temperature of boiling water. The dry mixture is then transferred
to a large glass tube, having a small hole in the bottom plugged with
glass wool to act as a filter, and light petroleum spirit--which boils
at about 150° to 180° Fahr.--is poured over it, till all the neutral or
unsaponifiable oil is dissolved out. In the other process no sand is
used, but the dry mixture is dissolved in water, and the soap solution
which holds the neutral oils in solution is treated with ether, which
dissolves out the neutral oil and then floats to the surface of the
liquid. The ether solution is then drawn off, and the ether in the one
case and petroleum spirit in the other are separated from the dissolved
oils by distillation, the last traces of these volatile liquids being
separated by blowing a current of filtered air through the flask
containing the neutral oil, which is then weighed and its percentage on
the original sample calculated.
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