Scientific American Supplement, No. 303, October 22, 1881Various
Science
Scientific American Supplement, No. 303, October 22, 1881
Various
Science -- Periodicals
n = height of the cylinder inclosing the air;
c = a factor which, multiplied by n, converts it into cubic
millimeters;
S = cubic contents of the meniscus;
d = difference of level between A and B, fig. 4;
= the pressure the air is under;
N = the cubic contents of the gauge in millimeters;
x = a fraction expressing the degree of exhaustion obtained; then
x=1/([N (760/d)]/[nc - S])
It will be noticed that the measurements are independent of the actual
height of the barometer, and if several readings are taken continuously,
the result will not be sensibly affected by a simultaneous change of the
barometer. Almost all the readings were taken at a temperature of about
20° C., and in the present state of the work corrections for temperature
may be considered a superfluous refinement.
_Gauge correction_.--It is necessary to apply to the results thus
obtained a correction which becomes very important when high vacua are
measured. It was found in an early stage of the experiments that the
mercury, in the act of entering the highly exhausted gauge, gave out
invariably a certain amount of air which of course was measured along
with the residuum that properly belonged there; hence to obtain the true
vacuum it is necessary to subtract the volume of this air from nc. By a
series of experiments I ascertained that the amount of air introduced by
the mercury in the acts of entering and leaving the gauge was sensibly
constant for six of these single operations (or for three of these
double operations), when they followed each other immediately. The
correction accordingly is made as follows: the vacuum is first measured
as described above, then by withdrawing all the boxes except the lowest,
the mercury is allowed to fall so as nearly to empty the gauge; it is
then made again to fill the gauge, and these operations are repeated
until they amount in all to six; finally the volume and pressure are a
second time measured. Assuming the pressure to remain constant, or that
the volumes are reduced to the same pressure,
v = the original volume; v' = the final volume;
V' = volume of air introduced by the first entry of the mercury;
V = corrected volume; then
V' = (v'-v)/6
V = v - [(v'-v)/6]
It will be noticed that it is assumed in this formula that the same
amount of air is introduced into the gauge in the acts of entry and
exit; in the act of entering in point of fact more fresh mercury is
exposed to the action of the vacuum than in the act exit, which might
possibly make the true gauge-correction rather larger than that given by
the formula. It has been found that when the pump is in constant use the
gauge-correction gradually diminishes from day to day; in other words,
the air is gradually pumped out of the gauge-mercury. Thus on December
21, the amount of air entering with the mercury corresponded to an
exhaustion of
1/27,308,805 .......Dec. 21.
1/38,806,688 ...... Dec. 29.
Public-domain text, read in full here on John Shaqi.
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