Scientific American Supplement, No. 315, January 14, 1882Various
Science
Scientific American Supplement, No. 315, January 14, 1882
Various
Science -- Periodicals
The presence of starch glucose in sugar-house molasses may be easily
detected by the optical saccharometer when the sirup has the usual
density of about 40 deg. B., and when starch sugar has been added in the
usual quantities.
For making the test the usual weight should be taken (16.35 grammes
for Duboscq's saccharometer, and 26.048 grammes for Ventzke's
instrument). The direct test should show a percentage of sugar not
higher than the number of Baume degrees indicating the density, and it
may be from 2 to 3 per cent. lower. To understand this, we must refer
to the composition of cane-sugar molasses of 40 deg. B.:
Sugar.......................................37.5
Insoluble impurities........................37.5
Water.......................................25
If the direct test should indicate 55 per cent. of sugar, and if the
molasses were straight, the composition would be--
Sugar...........................................55
Soluble impurities..............................20
Water...........................................25
Now, a product of this composition would not be a clear sirup at 40 deg.
B., but a mixture of sirup and crystals. Therefore, if the product is
a clear sirup at 40 deg. B., and it tests 55 per cent., it cannot be
_straight_.
The presence of starch glucose in sugar-house molasses may also be
detected by the copper test. The possibility of applying this test, as
well as those already indicated, rests on the fact that starch glucose
is always added in very large quantities for the purposes of
adulteration. A very small addition could not be satisfactorily
detected.
The detection by the copper test rests on the observation that very
nearly one-half of the soluble impurities in sugar-house molasses
consists of glucose in the shape of inverted sugar. We have seen above
that for a molasses of 40 deg. B. the soluble impurities amount to about
371/2 per cent. We may, then, lay down the rule: that the percentage of
glucose shown by the copper test cannot, in a straight sugar-house
molasses, be much greater than one-half of the number expressing the
density in Baume degrees. The reason is obvious from what has been
said of the test by the optical saccharometer.
* * * * *
FALSE VERMILION.--A curious case has been noticed in Germany,
where a small cargo of vermilion was purchased, and, upon being
analyzed, turned out to be red oxide of lead colored by eosine. This
is an entirely novel sophistication. The eosine was separated from the
oxide of lead by digesting the product for twenty-four hours in very
strong alcohol. A much shorter time is sufficient to color the spirit
enough to enable an expert chemist to detect the presence of this
splendid organic coloring matter. Another kind of "vermilion" consists
entirely of peroxide of iron, prepared especially to imitate the
brilliant and costly sulphide of mercury, which it does very well, and
is largely used in England, France, and America.
Public-domain text, read in full here on John Shaqi.
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