Scientific American Supplement, No. 315, January 14, 1882Various
Science
Scientific American Supplement, No. 315, January 14, 1882
Various
Science -- Periodicals
and ashes, and these impurities fell to the bottom of the water bath.
The gases after this process are divested of the greater part of any
tarry impurities which they may have possessed, and are ready for the
final purification, in which ammonia is extracted. This is effected by
means of a series of shallow trays, covered with water or weak acid,
and pierced with a number of fine holes, through which the gas is made
to bubble. The washing apparatus is therefore strangely similar in
principle to that designed by Mr G. Livesey. M. Chevalet states that
this double process is applicable to gas works as well as to the
purification of smoke, with the difference that for the latter purpose
the washing trays are filled with acid for the retention of ammonia,
while in the former application gas liquor or water is used. The
arrangement is said to be a practical success.--_Journal of Gas
Lighting._
* * * * *
DETERMINATION OF NITROGEN IN HAIR, WOOL, DRIED BLOOD, FLESH MEAL,
AND LEATHER SCRAPS.
BY DR. C. KRAUCH.
Differences obtained in the estimation of nitrogen in the above
substances are frequently the source of much annoyance. The cause of
these discrepancies is chiefly due to the lack of uniformity in the
material, and from its not being in a sufficiently fine state during
the combustion. The hair which is found in commerce for the
manufacture of fertilizers, is generally mixed with sand and dust.
Wool dust often contains old buttons, pieces of wood, shoe pegs, and
all sorts of things. The flesh fertilizers are composed of light
particles of flesh mixed with the heavier bone dust.
Even after taking all possible precautions to finely comminute these
substances by mechanical means, still only imperfect results are
obtained, for the impurities, that is to say, the sand, can never be
so intimately mixed with the lighter particles that a sample of 0.5 to
0.8 gramme, such as is used in the determination of nitrogen, will
correspond to the correct average contents. In substances such as
dried blood, pulverization is very tedious. A very good method of
overcoming these difficulties, and of obtaining from the most mixed
substances a perfectly homogeneous mass, is that recommended by
Grandeau[1] of decomposing with sulphuric acid--a method which as yet
does not seem to be generally known. From a large quantity of the
substance to be examined, the coarse stones, etc., are removed by
picking or sifting, and the prepared substance, or in cases where the
impurities cannot be separated, the original substance, is treated
with sulphuric acid; after it is decomposed, the acid is neutralized
with calcium carbonate, and the nitrogen is determined in this mass.
[Footnote 1: _Handbook d. Agrict. Chem. Analyst._, p. 18.]
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