Scientific American Supplement, No. 315, January 14, 1882Various
Science
Scientific American Supplement, No. 315, January 14, 1882
Various
Science -- Periodicals
In order to operate rapidly, it is best to use as little sulphuric
acid as possible. If too much sulphuric acid is used, necessarily a
large amount of calcium carbonate is essential to get it into proper
condition for pulverizing. Under such circumstances the percentage of
nitrogen becomes very low, and a slight error will become
correspondingly high.
20 c.c. of concentrated sulphuric acid and 10 c.c. are sufficient for
30 to 40 grammes of material. After the substance and liquid have been
thoroughly stirred in a porcelain dish, they are warmed on a water
bath and continually stirred until the mass forms a homogeneous
liquid. The sirupy liquid thus obtained is then mixed with 80 to 100
grammes of pulverized calcium carbonate (calcspar), dried for fifteen
minutes at 40 to 60 deg. C., and after standing for one to two hours the
dish and its contents are weighed. From the total weight the weight of
the dish is subtracted, which gives the weight of the calcium sulphate
and the calcium carbonate, and the known weight of the wool dust, etc.
This material is then intimately ground, and 2 to 3 grammes of it are
taken for the determination of the nitrogen, which is then calculated
for the original substance.
Although the given quantities of water and sulphuric acid hardly
appear sufficient for such a large quantity of hair or wool, still in
the course of a few minutes to a quarter of an hour, after continual
stirring, there is obtained a liquid which, after the addition of the
calcium carbonate, is readily converted into a pulverized mass.
Frequently a smaller quantity of sulphuric acid will suffice,
especially if the material is moist. The chief merit of this process
is that in a short time a large quantity of material, having a uniform
character, is obtained. Its use is, therefore, recommended for general
employment.
When the coarser stones, etc., are weighed, and the purified portion
decomposed, absolutely correct results are obtained, and in this way
the awkward discrepancies from different analysts may be
avoided.--_Chemiker Zeitung_, v. 7, p. 703.
* * * * *
TESTING WHITE BEESWAX FOR CERESINE AND PARAFFINS.
BY A. PELTZ.
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