Scientific American Supplement, No. 358, November 11, 1882Various
Science
Scientific American Supplement, No. 358, November 11, 1882
Various
Science -- Periodicals
Up to recent times, chloride of methyl in a free state had received
scarcely any industrial application, by reason of the difficulty of
preparing it in a state of purity at a low price. Mr. C. Vincent,
however, has made known a process which permits of this product being
obtained abundantly and cheaply. It consists in submitting to the action
of heat the hydrochlorate of trimethylamine, which is obtained as a
by-product in the manufacture of potash of beets. The hydrochlorate
is thus decomposed into free trimethylamine, ammonia, and chloride
of methyl. A washing with hydrochloric acid takes away all traces of
alkali, and the gas, which is gathered under a receiver full of water,
may afterward be dried by means of sulphuric acid, and be liquefied by
pressure.
[Illustration: VINCENTS ICE MACHINE. FIG. 2.--THE FREEZER (Transverse
Section).]
Pure liquid chloride of methyl is now an abundant product. There are two
uses to which it is applied: first, for producing cold, and second, for
manufacturing coal tar colors.
[Illustration: VINCENTS ICE MACHINE. FIG. 3.--HALF PLAN OF FREEZER]
At present we shall occupy ourselves with the first of such
applications--the production of cold.
The apparatus serving for the production of cold by this material are
three in number: (1) the _freezer_ (Figs. 1, 2, and 3), in which is
produced the lowering of temperature that converts into ice the water
placed in carafes or any other receptacles; (2) the _pump_ (Figs. 4, 5,
and 6), which sucks the chloride of methyl in a gaseous state up into
the freezer and forces it into the liquefier; and (3) the _liquefier_,
which is nothing else than a spiral condenser in which the chloride of
methyl condenses, and from thence returns to the freezer to serve anew
for the production of cold.
[Illustration: VINCENTS ICE MACHINE. FIG. 4.--THE PUMP (Longitudinal
Section).]
_The Freezer_.--This consists of a rectangular iron tank, 1 meter x 1
meter x 1.5 meters, containing a galvanized plate iron cylinder, A, kept
in place by iron supports. This cylinder contains 24 horizontal tubes,
which are open at the ends and riveted to vertical plates like those of
tubular steam boilers. The tank is filled with a mixture of water and
chloride of calcium, forming, as well known, an incongealable liquid.
Into this liquid are plunged the receptacles containing the water to be
converted into ice. The chloride of methyl is introduced through the
cock, B, into the body of the cylinder, A, and surrounds and cools the
tubes, as well as the incongealable liquid uninterruptedly circulating
in the latter, by means of a helix, C, set in motion by a belt from the
shop. This liquid is thus greatly lowered in temperature and freezes the
water in the receptacles.
[Illustration: VINCENTS ICE MACHINE. FIG. 5.--VERTICAL SECTION OF THE
PUMP.]
_The Pump_.--The pump in the larger apparatus has two chambers of
unequal diameter, that is to say, it operates after the manner of
compound engines.
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