Scientific American Supplement, No. 358, November 11, 1882Various
Science
Scientific American Supplement, No. 358, November 11, 1882
Various
Science -- Periodicals
M. Dumas called the attention of the Academy to this point, in
connection with its mission of selecting suitable stations for observing
the transit of Venus. The process and apparatus of Muentz and Aubin
offer the means adapted for making these experiments, and seem
sufficient to solve the problem which science proposes, of determining
the present quantity of carbonic acid in the air.
If these experiments yield satisfactory results, as we have good reasons
to believe they will, it is to be hoped that annual observations will be
made in properly-chosen places, so as to determine the variations which
may possibly take place in the relative quantity of atmospheric carbonic
acid during the coming century.--_Compt. Rend_., p. 589.
[Although this proposition was made by a Frenchman to his fellow
scientists, would it not be well for some American to accept the
challenge, and bring it before the coming meeting of the American
Association for the Advancement of Science, in the hope that we,
too, may contribute our mite of effort in the same direction?--_Ed.
Knowledge_.]
* * * * *
THE INFLUENCE OF AQUEOUS VAPOR ON THE EXPLOSION OF CARBONIC OXIDE AND
OXYGEN.
[Footnote: Read before the British Association, Southampton Meeting,
Section B, 1882.]
By HAROLD B. DIXON, M.A., Millard Lecturer in Chemistry, Balliol and
Trinity Colleges, Oxford.
Two years ago I had the honor of showing before the Chemical Section of
the British Association some experiments, in which a well-dried mixture
of carbonic oxide and oxygen was submitted to electric sparks without
exploding.[1] It was further shown that the introduction of a very
minute quantity of aqueous vapor into the non-explosive mixture was
sufficient to cause explosive combination between the gases when the
spark was passed. The hypothesis advanced to account for the observed
facts was that carbonic oxide does not unite directly with oxygen at
a high temperature, but only indirectly through the intervention of
water-vapor present, a molecule of water being decomposed by one of
carbonic oxide to form a molecule of carbonic acid and one of free
hydrogen, and the latter uniting with the oxygen to re-form a molecule
of water, which again undergoes the same cycle of changes, till all the
oxygen is transferred to the carbonic oxide:
H_{2}O + CO = H_{2} + CO_{2}
H_{2} + O = H_{2}O
[Footnote 1: "Report of British Association," 1880, p. 503.]
For such a series of reactions a _comparatively_ few molecules of water
would suffice, and the change produced by their alternate reduction and
oxidation would come under the old term of "catalytic action," inasmuch
as the few water molecules present at the beginning are found in the
same state at the completion of the reaction.
Public-domain text, read in full here on John Shaqi.
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