Scientific American Supplement, No. 362, December 9, 1882Various
Science
Scientific American Supplement, No. 362, December 9, 1882
Various
Science -- Periodicals
Until lately I have always added excess of chlorate of potash to the
residue left in a, evaporated it nearly to dryness, diluted, filtered,
and added chloride of barium to the diluted filtrate, but only once
have I obtained a trace of precipitate after standing 48 hours, and the
pig-iron in that case contained 8 per cent. of silicon, so that all
the sulphur is evolved during the process. It has been objected to the
evolution process that when the iron contains copper all the sulphur is
not evolved, but theoretically it ought to be evolved whether copper is
present or not; and to test the point I fused 3 lb. of ordinary Scotch
pig-iron with some copper for half an hour in a Fletcher's gas furnace.
No copper could be detected in the iron by mere observation with a
microscope, but it gave on analysis 0.225 per cent. of copper, and on
estimating the sulphur in it by the above process and by oxidation with
chlorate of potash and hydrochloric acid, using 100 grains in each case,
and performing blank experiments, I found:
By peroxide of hydrogen process 0.0357 per cent.
By oxidation (KClO_{3} and HCl) process, 0.0302 "
so that even in highly cupriferous pig-iron all the sulphur is evolved
on treatment with strong hydrochloric acid.--_Chem. News_.
* * * * *
THE AIR IN RELATION TO HEALTH.
[Footnote: Abstract of a lecture before the Master Plumbers'
Association, New York, Nov. 2. 1882.]
By Prof. C. F. CHANDLER.
It is only about one hundred years since the first important facts were
discovered which threw light upon the chemistry of atmosphere. It was in
1774 that Dr. Priestley, in London, and Scheele, in Sweden, discovered
the vital constituents of the atmosphere--the oxygen gas which supports
life. The inert gas, nitrogen, had been discovered a year or two before.
When we examine our atmosphere, we find it is composed of oxygen and
nitrogen. The nitrogen constitutes no less than 80 per cent, of the
atmosphere; the remaining 20 percent, consists of oxygen, so that the
atmosphere consists almost entirely of these two gases, odorless and
colorless and invisible. The atmosphere is, however, never free from
moisture; a certain amount of aqueous vapor is always present. The
quantity can hardly be stated, as it varies from day to day and month
to month; it depends upon the temperature and other conditions. Then
we have the gas commonly called carbonic acid in extremely minute
quantities, about one part in 2,500, or four one-hundredths of one per
cent. A small quantity of ammonia and a small quantity of ozone are also
present.
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