Scientific American Supplement, No. 363, December 16, 1882Various
Science
Scientific American Supplement, No. 363, December 16, 1882
Various
Science -- Periodicals
Saffranine is detected by the action of hydrochloric acid, which turns
it to a beautiful blue; the red color is restored by washing in water.
Azo-dinaphthyl diamine is recognized by its peculiar orange cast, and is
turned by hydrochloric acid to a dull, dirty violet. Rosolic acid and
coralline, as well as eosine, are turned by hydrochloric acid to an
orange-yellow: the two former are distinguished from eosine by their
shade, which inclines to a yellow. Potassa turns rosolic acid and
coralline from an orange-red to a bright red, while it produces no
change in eosine. If the action of potassa is prolonged, modified eosine
is blackened in consequence of the decomposition of the wool, the
sulphur of which forms lead sulphide. Coccine becomes of a light
lemon-yellow on treatment with hydrochloric acid. Washing with water
restores the original shade. It affords the same reactions as eosine,
but its tone is more inclined to an orange.
Artificial ponceau does not undergo any change on treatment with
hydrochloric acid, and resists potash. Red wood shades are turned toward
a gooseberry-red by hydrochloric acid, especially if strong. This last
reaction not being very distinct, red-wood shades might be mistaken
for those of artificial ponceau but for the superior brightness of the
latter. If the action of potassa is prolonged, the red-wood shades
are decolorized, and a washing with water then bleaches the tissue.
Rocelline affords the same reactions as artificial ponceau, but if
steeped in a concentrated solution of stannous chloride it is in time
completely discharged, which is not the case with artificial ponceau.
VIOLET COLORS.
Violets are divided into two groups: those affected by potassa, and
those upon which it has no action. The first group embraces logwood,
orchil, alkanet, and aniline violets, including under the latter term
Perkin's violet, (probably the original "mauve"), dahlia, Parme or
magenta violet, methyl, and Hofmann's violets. The action of potassa
gives indications for each of these violets. Logwood violet is browned;
that of orchil, if slightly reddish, is turned to a blue-violet; that of
alkanet is modified to a fine blue. Lastly, Perkin's mauve, dahlia, and
methyl violet become of a grayish brown, which may be re-converted into
a fine violet by washing in abundance of water. When the shades are
very heavy, this grayish brown is almost of a violet-brown, so that the
violets might seem to be unaltered.
The action of hydrochloric acid distinguishes these colors better still
if the aid of ammonia is called in for two cases.
Public-domain text, read in full here on John Shaqi.
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