Scientific American Supplement, No. 392, July 7, 1883Various
Science
Scientific American Supplement, No. 392, July 7, 1883
Various
Science -- Periodicals
As soon as the color has been observed, the test glass is put in a water
bath at the full boiling temperature and left there five minutes. It was
found that the action of nitric acid upon cotton seed and sesame oil was
the most violent, sometimes so violent as to throw the oil out of the
glass. At the end of another five minutes after the test tube is taken
out of the water bath, the following colors are seen: olive and rape
oils are red; castor oil is golden yellow; sun flower oil, reddish
yellow; sesame and peanut, brownish yellow; cotton seed, reddish brown.
After standing 12 to 18 hours at about 60° Fahr. the olive, rape, and
peanut oils will have solidified; sun flower, castor, and cotton seed
will be like salve (sticky), while sesame will remain perfectly liquid.
Mixtures of olive oil with small quantities of cotton seed or sesame are
distinguished by this characteristic--that, although the whole mass,
which is darker in color than olive oil, solidifies at first, at the end
of 24 or 36 hours a brown oil will be found floating upon the surface of
the solid mass, while the lower strata exhibit the yellow color of pure
olive oil. Oil of rosemary has no effect when shaken with cold nitric
acid, and imparts to it only a slightly darker color on heating. Oils
treated with lye act just like pure oils.
Far the purpose of determining the melting point of the fatty acids, 10
grammes of oil were saponified with 5 grammes of caustic potash on the
water bath; some water and alcohol being added. After all the alcohol
had been expelled the soap was dissolved in hot water, and the fatty
acids separated from the clear solution by adding hydrochloric acid.
After prolonged heating these acids will swim on the salt solution as
a perfectly clear oil, a portion of which is then put into a little,
narrow, thin walled tube and allowed to solidify. The point at with it
melts and solidifies is determined by putting this tube in a beaker
glass filled with water and warming with a small flame. A thermometer
is placed _in_ the fatty acids and moved gently about during the
observation, and the point accurately observed at which the whole mass
becomes perfectly clear, and also when the mercury bulb begins to be
clouded. It was found that the acids from pure olive oil melt between
26½ and 28½° C. (= 80° to 83° Fahr.) and solidify at a point not lower
than 22° C. (72° Fahr.). The melting point of the fatty acids in the
oils used to adulterate olive oil differs considerably from this. The
melting and solidifying points of the acids in cotton seed, sesame,
and peanut oils lie considerably higher, those of sunflower, rape, and
castor oils decidedly lower than those of olive oil.
The melting and solidifying points of these acids are as follows:
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account