Scientific American Supplement, No. 392, July 7, 1883Various
Science
Scientific American Supplement, No. 392, July 7, 1883
Various
Science -- Periodicals
Cotton seed melts at 38.0°C. solidifies 35.0°C.
Sesame do. 35.0 do. do. 32.5 do.
Peanut do. 33.0 do. do. 31.0 do.
Sunflower do. 23.0 do. do. 17.0 do.
Rape do. 20.7 do. do. 15.0 do.
Castor oil do. 13.0 do. do. 2.0 do.
The above figures differ so much from those of olive oil, that
adulteratious carried to the extent that they are in trade can easily
be detected by the aid of an estimation of the melting point, for a
Gallipoli olive oil, mixed with 20 per cent. of sunflower oil, melted at
24° C. and solidified at 18° C. (of course, the fatty acids are meant).
A Nizza oil, mixed with 20 per cent. cotton seed oil, melted at 31½° C.
and solidified at 28° C. A Gallipoli oil with 33-1/3 per cent. of rape
oil melted at 23½° C. and solidified at 16½° C. When 0.50 per cent. of
rape is added, it melts as low as 20° and solidifies at 13½° C., etc.
In testing the solubility of the fatty acids in alcohol and acetic acid,
I employ the method proposed by David (in _Comptes Rendus_, 1878, p.
1416) for estimating stearic acid.
It depends upon the principle that when acetic acid is poured drop by
drop into an alcoholic solution of oleic acid, there comes a time when
all the oleic acid separates, but stearic acid, which is insoluble in
a mixture of alcohol and acetic acid, remains insoluble if the mixture
contains oleic acid.
The following manipulations are adopted in testing olive oil: Equal
parts of glacial acetic acid and water are mixed in a bottle. Then 1
c.c. of pure oleic acid, 3 c.c. of 95 per cent. alcohol, and 2 c.c.
of acetic acid are put in a small tube graduated in tenths of cubic
centimeters. The solution should remain clear; on adding another
one-tenth c.c. of acetic acid it becomes turbid, and when 1 c.c. of
oleic acid (or at first even more) floats on the mixture of acid and
alcohol, the liquid is ready for use. If this is not the case, the
proportions (of acetic acid and alcohol?) must be varied until the
addition of one-tenth c.c. of the former will cause all the oleic
acid to separate. The proportions having been ascertained from
these preliminary experiments, the alcohol and acid are then mixed
accordingly, e.g., 300 of alcohol to 225 of acid. One or two grammes
of stearic acid are added to the alcoholic acetic acid, and the clear
supernatant liquid used for the experiments.
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