Scientific American Supplement, No. 392, July 7, 1883Various
Science
Scientific American Supplement, No. 392, July 7, 1883
Various
Science -- Periodicals
One cubic centimeter of the oil (acids) to be tested is put in the tube,
and 15 c.c. of alcoholic acetic acid added, well shaken, and the whole
left to stand quietly at 15° C. (60° Fahr). If the olive oil is pure,
the acids dissolve to a clear solution that remains so. Cotton seed
oil is insoluble, and the solution obtained by heating the solution
solidifies at 60° Fahr. to a white jelly. Sesame and peanut oil react
in a similar manner. Sunflower oil dissolves, but at 60° a granular
precipitate falls. Rape oil is entirely insoluble and floats like oil on
the surface. Castor oil on the contrary dissolves completely, just like
olive oil, and hence cannot be detected therein by this method. To
detect this oil we must take the melting point of the acids along with
the solubility of the oil itself in alcohol.
Olive oil when mixed with 25 per cent. of cotton seed oil yields a
granular precipitate, and so does 25 per cent. of sesame. Smaller
quantities cannot be detected by these methods. For rape oil the limit
is 50 per cent., and in smaller quantities the oil does not collect on
the alcoholic solution. The decided lowering of the melting point of
the fatty acids in combination with the sulphur reaction, and the
insolubility of the oil in alcohol, also furnish a method of detecting
when present in smaller quantities in olive oil.
Although I am well aware that I am making public a research that is by
no means free from objections, I nevertheless believe that it may be of
use to those who have to undertake the ticklish and intricate analyses
of commercial fats.--_Translated from the Chemiker Zeitung_, p. 355.
Leipsic, Jan., 1883.
* * * * *
ON THE THEORY OF THE FORMATION OF COMPOUND ETHERS.
In a note presented to the Industrial Society of Mulhouse, A. Pabst
discusses the different stages in the formation of compound ethers, as
Williamson has explained the production of ordinary ethers by the action
of sulphuric acid upon alcohol. Pabst has observed that the compound
ethers are formed in an analogous manner. If alcohol, sulphuric acid,
and acetic acid are heated together, acetic ether, we know, is formed.
Pabst has shown that it takes place in three stages. In the first stage,
ethyl sulphuric acid and water are formed; in the second, acetate of
ethyl with the reproduction of sulphuric acid, which again converts a
fresh quantity of alcohol into ethyl sulphuric acid.
(1) C_{2}H_{5}OH+HO,SO_{2}OH = C_{2}H_{5}O,SO_{2}OH+H_{2}O.
(Alcohol.) (Sulphuric acid.) (Ethyl sulphuric acid.)
(2) C_{2}H_{5}O,SO_{2}OH+C_{2}H_{3}O,OH =
(Ethyl sulphuric acid.) (Acetic acid.)
C_{2}H_{5}O,C_{2}H_{3}O+HO,SO_{2}HO.
(Acetate of ethyl.) (Sulphuric acid.)
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