Scientific American Supplement, No. 433, April 19, 1884Various
Science
Scientific American Supplement, No. 433, April 19, 1884
Various
Science -- Periodicals
Hydrogen, although a gas, is recognized by chemists as a metal, and when
combined with any solid metal--as in the case known to electricians as
the polarization of a negative element,--the compound may correctly be
termed an alloy; while any compound of hydrogen with the fluid metal
mercury may with equal correctness be termed an amalgam of hydrogen, or
"hydrogen amalgam." The efforts of many chemists and mining engineers
have for many years been devoted to a search for some effective and
economical means for preventing the "sickening" of mercury and its
consequent "flouring" and loss. Some sixteen or more years ago,
Professor Crookes, F.R.S., discovered and, after a series of
experiments, patented the use of an amalgam of the metal sodium for this
purpose. He made the amalgam in a concentrated form, and it was added
in various proportions to the mercury used for gold amalgamation. Water
becoming present, it will readily be understood that the sodium, in
being converted into the hydrate (KHO) of that metal, caused a rapid
evolution of hydrogen. The hydrogen thus evolved was the excess over a
certain proportion which enters into combination with the mercury. While
the mercury retained the charge of hydrogen, the "quickness" of the
fluid metal was preserved; but upon the loss of the hydrogen the
"quickness" ceased, and the mercury was acted upon by the injurious
components contained in the ore.
Since the introduction of the sodium amalgam, many attempts have been
made, more especially in America, to overcome the tendency of mercury to
"sicken" and lose its "quickness." The greater number of these efforts
have been made by the use of electricity as the active agent in
attaining this end; but such efforts have been generally of a crude and
unscientific character. Latterly Mr. Barker, of the Electro-amalgamator
Company, Limited, has introduced a system--already detailed in these
pages--by which the mercury is "quickened." In his method the running
water passing over the tables, or other apparatus of a similar
character, is used as the electrolyte. In this arrangement, the mercury
being the cathode, plates or wires of copper constituting anodes are
brought into contact with the water passing over the mercury in each
"riffle." Both the cathode and the anodes are, of course, maintained in
contact with the poles of a suitable source of electrical supply. The
current then passes from the copper anode through the running water
to the mercury cathode, and so on to the negative pole of the
electro-motor. As a consequence of this arrangement, hydrogen is evolved
from the water, and has the effect of reducing any oxide or other
detrimental compound of the metal; in other words, it "quickens" and
prevents "sickening" of the fluid metal, and consequent "flouring" and
loss. While the hydrogen is evolved at the cathode, oxygen enters into
combination with the copper constituting the anodes. This to some extent
impairs the conductivity of the circuit.
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