Scientific American Supplement, No. 433, April 19, 1884Various
Science
Scientific American Supplement, No. 433, April 19, 1884
Various
Science -- Periodicals
The latest process, however, is that of Mr. Bernard C. Molloy, M.P.,
which we have already characterized as highly scientific and effective,
the production of a suitable amalgam being obtained under the most
economical and simple conditions. This process has the advantage of
producing not only a hydrogen amalgam, but also at will an amalgam of
hydrogen combined with any metal electro-positive to this latter. Thus
hydrogen potassium or hydrogen sodium can be obtained, as will be seen
by the following description.
Mr. Molloy's effort appears to have been, in the first place, directed
to a system which could be adapted to any existing apparatus, and in
certain cases where water was scarce, to avoid altogether the use of
that, in some districts, rare commodity. For the purpose of explanation
we select an ordinary amalgamating table fitted with mercury riffles.
The surface of the table is in no way interfered with or disturbed. The
bed of the riffle, however, is constructed of some porous material, such
as leather, non-resinous wood, or cement, which serves as the diaphragm
upon which the mercury rests, and separates the fluid metal from the
electrolyte beneath. Running the full length of the table is a thin
layer of sand, supported and pressing against the diaphragm, and lying
in this sand is the anode, formed preferably of lead. A peroxide of
that metal is formed by the action of the currents, and may be readily
reduced for use over and over again after working for from one to three
months. The peroxide of lead, as is well known, is a conductor of
electricity, and this fact constitutes an important advantage in the
working of the process. The thin layer of sand is saturated with an
electrolyte, such as dilute sulphuric acid (H_{2}SO_{4} + 20H_{2}O)
to give a simple hydrogen amalgam; (Na_{2}SO_{4} + xH_{2}O) to give a
hydrogen sodium amalgam; or (K_{2}SO_{4} + xH_{2}O) to give a hydrogen
potassium amalgam. Numerous other electrolytes constituted by acids,
alkalies, and salts can be used to form an amalgam permanently
maintained in a condition of "quickness" and freed from all liability
to "sicken," whatever the components of the ore may be. The mercury
is connected with the negative pole of the voltaic battery or other
electro-motor, and the lead made with the positive pole of the same
source. When the current passes there is formed according to the nature
of the electrolyte, a hydrogen amalgam, or an amalgam of hydrogen with a
metal electro-positive to hydrogen. The electrolyte, which, it will be
understood, is distinct and apart from the body of water passing over
the table, will last almost indefinitely, there being no consumption of
any of its constituents, excepting hydrogen and oxygen from the water
of solution. The quantity of acid or saline material contained in the
electrolyte is so very small that there can be no difficulty in finding
a supply in any district. The question of the supply of electricity is
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