Scientific American Supplement, No. 441, June 14, 1884.Various
Science
Scientific American Supplement, No. 441, June 14, 1884.
Various
Science -- Periodicals
" field of 30 deg.. | 30 | 24 | 2.25 |7 _a b_
6. " field of 20 deg.. | 20 | 27 | 1.96 |7 _a c_
---------------------------------------+------+---------+------+------
As an analyzing prism of about 6 mm. clear width, and 13.5 mm. long,
the new prism is stated by its inventor to be of the most essential
service, and it would certainly appear that the arrangement is rather
better adapted for small prisms than for those of considerable size.
Any means by which a beam of polarized light of large diameter--say 3
to 31/2 inches--could be obtained with all the convenience of a Nicol
would be a real advance, for spar of sufficient size and purity for
such a purpose has become so scarce and therefore so valuable that
large prisms are difficult to procure at all. So far as an analyzer is
concerned, the experience of the writer of this notice would lead to
the opinion that improvements are to be looked for rather in the way
of the discovery of an artificial crystal which absorbs one of the
polarized rays than by further modifications depending upon total
reflection. The researches of Dr. Herapath on iodosulphate of quinine
(_Phil. Mag._, March, 1852, 161, and November, 1853, 346) are in this
direction; but crystals of the so-called herapathite require great
manipulative skill for their production. If these could be readily
obtained of sufficient size, they would be invaluable as analyzers.
This opinion is supported by the existence of an inconvenience which
attends every form of analyzing prism. It is frequently, and
especially in projecting apparatus, required to be placed at the focus
of a system of lenses, so that the rays may cross in the interior of
the prism. This is an unfavorable position for a prismatic analyzer,
and in the case of a powerful beam of light, such as that from the
electric arc, the crossing of the rays within the prism is not
unattended with danger to the cementing substance, and to the surfaces
in contact with it.
PHILIP R. SLEEMAN.
* * * * *
ZIRCON.
By F. STOLBA.
Finely ground zircon is quickly rendered soluble if fused with a
mixture of potassium borofluoride and potassium carbonate. The author
takes two parts of the former to three of the latter, and prepares an
intimate, finely divided mixture, which is kept ready for use.
Of this mixture four parts are taken to one of zircon, thoroughly
mixed, and melted in a platinum crucible at a red heat. The mass fuses
readily, froths at first and gives off bubbles of gas, and flows then
quietly, forming a very fluid melt. If the zircon is finely ground, 15
minutes are sufficient for this operation. The loss of weight is 16
per cent., and is not notably increased on prolonged fusion. It
corresponds approximately to the weight of the carbonic anhydride
present in the potassium carbonate.
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