Scientific American Supplement, No. 460, October 25, 1884Various
Science
Scientific American Supplement, No. 460, October 25, 1884
Various
Science -- Periodicals
This is, in fact, all we have of the kinetic theory of gases up to the
present time, and this has done for us, in the hands of Clausius and
Maxwell, the great things which constitute our first step toward a
molecular theory of matter. Of course from it we should have to go on to
find an explanation of the elasticity and all the other properties of the
molecules themselves, a subject vastly more complex and difficult than the
gaseous properties, for the explanation of which we assume the elastic
molecule; but without any explanation of the properties of the molecule
itself, with merely the assumption that the molecule has the requisite
properties, we might rest happy for a while in the contemplation of the
kinetic theory of gases, and its explanation of the gaseous properties,
which is not only stupendously important as a step toward a more
thoroughgoing theory of matter, but is undoubtedly the expression of a
perfectly intelligible and definite set of facts in Nature.
But alas for our mechanical model consisting of the cloud of little elastic
solids flying about among one another. Though each particle have absolutely
perfect elasticity, the end must be pretty much the same as if it were but
imperfectly elastic. The average effect of repeated and repeated mutual
collisions must be to gradually convert all the translational energy into
energy of shriller and shriller vibrations of the molecule. It seems
certain that each collision must have something more of energy in
vibrations of very finely divided nodal parts than there was of energy in
such vibrations before the impact. The more minute this nodal subdivision,
the less must be the tendency to give up part of the vibrational energy
into the shape of translational energy in the course of a collision; and I
think it is rigorously demonstrable that the whole translational energy
must ultimately become transformed into vibrational energy of higher and
higher nodal subdivisions if each molecule is a continuous elastic solid.
Let us, then, leave the kinetic theory of gases for a time with this
difficulty unsolved, in the hope that we or others after us may return to
it, armed with more knowledge of the properties of matter, and with sharper
mathematical weapons to cut through the barrier which at present hides from
us any view of the molecule itself, and of the effects other than mere
change of translational motion which it experiences in collision.
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