Scientific American Supplement, No. 467, December 13, 1884Various
Science
Scientific American Supplement, No. 467, December 13, 1884
Various
Science -- Periodicals
A piece of thin paper is placed on the curved glass, and the ground
glass pushed close up and fixed by two small wedges, D. The paper
is then slipped out, leaving a narrow, even opening between the two
glasses. The width of this opening can be varied by using thicker paper
if the plates require to be coated with a thicker film. By using this
form the coater can be more easily cleaned, as the ground glass can be
slipped right out at the back, and probably in passing from the opening
to the plates over the curved glass the wave of the emulsion will be
equalized as well as when passing through the muslin.
IODO-CHLORIDE OF SILVER EMULSION.
By V. SCHUMANN.
In a recent paper in the _Wochenblatt_, says the _Photographic
News_, this investigator relates his experience of gelatine emulsion
containing chloride and iodide of silver. Gelatine films containing
pure chloride of silver can only be used in the camera in exceptional
cases; if, however, iodide be added, the resulting iodo-chloride
films answer most of the purposes of a gelatino-bromide plate. It may
be remarked that with gelatino-chloride emulsion an image is easily
developed with pyro or oxalate; but unfortunately, fogging is very
liable to set in. On strongly diluting the developing solution and
adding a large proportion of bromide, it is possible to obtain a
clear deposit, but the image is so thin that it is quite useless for
practical purposes.
Gelatino-iodide films possess totally different properties. The
development is extremely slow, without any tendency to fog; thus the
addition of a restrainer should be avoided. Iodo-chloride emulsion can
be prepared either by dissolving the chloride and iodide salts in the
gelatine solution, and then adding by degrees the silver nitrate; or
by making two separate emulsions of chloride and iodide of silver, and
then mixing the two after the washing process. It should be noted that
the properties of a compound or a mixture of the two haloids are very
different. A negative of the spectrum impressed on an iodo-chloride
film, prepared by mixing the two emulsions, shows two colored deposits.
The red end of the spectrum as far as the G line is reproduced in
the negative as a red tone, while that part of the spectrum from G
extending to the violet appears as a grayish violet deposit. When using
Stolze's potash developer, the difference of the two tones on the
negative appears even more marked.
Experiments were instituted to determine the most suitable proportion
of the silver haloids to be suspended in the emulsion. For this purpose
three emulsions were prepared according to the following formulæ:
No. 1.--IODO-CHLORIDE EMULSION.
A.--Ammonium chloride 0.64 gramme.
Potassium iodide 0.05 "
Gelatine 1.5 "
Water 15 c. c.
B.--Silver nitrate 1.55 gramme.
Water 15 c. c.
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