Scientific American Supplement, No. 467, December 13, 1884Various
Science
Scientific American Supplement, No. 467, December 13, 1884
Various
Science -- Periodicals
The precipitation of tannin by a solution of gelatin is effected
more completely and in a better condition for filtration if, besides
ammonium chloride, as proposed by Schulze and Lehmann, there is also
added a small quantity of chromium sulphate or of chrome-alum. The
author proceeds in the same manner as Lehmann, but he adds to 100 c.c.
of the solution containing sal-ammoniac from 5 to 8 drops of a solution
containing 1 part chromium sulphate in 25 parts of water. In order to
ascertain the end of the reaction, he filters small quantities into two
test glasses of equal width, adds to the one a few drops of a solution
of gelatin, observing if the two liquids, when held up against a sheet
of black glazed paper, appear opaque or transparent. As long as a
precipitate is formed, these portions and the washings of the little
filters are poured back to the main quantity. If acetic or tartaric
acid is present, the liquid should be neutralized before proceeding to
the determination. Johanson points out that, though this method gives
good results with the tannin of galls and of oak-bark, an extract
of coffee gives no precipitate with solution of gelatin, so that
caffeo-tannic acid cannot be determined in this manner. This shows that
only quantities of tannin of one and the same kind can be compared with
each other.
THE INCOMPLETE COMBUSTION OF GASES.
By HAROLD B. DIXON, M.A.
[Abstract of a paper read before the Chemistry Section of the British
Association at Montreal.]
The author gave a _resume_ of the work he had done in continuation of
the researches of Bunsen, E. von Meyer, Horstmann, and other chemists,
on the division of oxygen when exploded with excess of hydrogen and
carbonic oxide. The following are the general conclusions arrived at:
1. No alteration _per saltum_ occurs in the ratio of the products
of combustion. The experiments made completely confirm Horstmann's
conclusion; Bunsen's earlier experiments being vitiated by the presence
of aqueous vapor in the eudiometer.
2. A dry mixture of carbonic oxide and oxygen does not explode when
an electric spark is passed through it. The union of carbonic oxide
is effected indirectly by steam. A mere trace of steam renders the
admixture of carbonic oxide and oxygen explosive. The steam undergoes
a series of alternate reductions and oxidations, acting as a "carrier
of oxygen" to the carbonic oxide. With a very small quantity of steam
the oxidation of carbonic oxide takes place slowly; as the quantity of
steam is increased, the rapidity of explosion increases.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account