Scientific American Supplement, No. 467, December 13, 1884Various
Science
Scientific American Supplement, No. 467, December 13, 1884
Various
Science -- Periodicals
The silver alloys with aluminum bronze, as represented in the four
following atomic formulas, are of a rich gold color, and well adapted
for jewelry, watch cases, etc.:
Cu Al Ag
Ag + 24 (Al + Cu_{6}) = 0.9180 + 0.0616 + 0.0203
Ag + 24 (Al + Cu_{7}) = 0.9241 + 0.0570 + 0.0188
Ag + 24 (Al + Cu_{8}) = 0.9330 + 0.0504 + 0.0166
Ag + 24 (Al + Cu_{9}) = 0.9400 + 0.0450 + 0.0150
The figures being proportional weights.
A cheap alloy for journal boxes and machinery may be made by
substituting zinc for silver in the following atomic proportions:
Cu Al Zn
Zn + 2(Al + Cu_{6}) = 0.8643 + 0.0622 + 0.0734
Zn + 2(Al + Cu_{9}) = 0.9053 + 0.0435 + 0.0512
Zn + 2(Al + Cu_{12}) = 0.9273 + 0.0333 + 0.0394
This is subject to considerable shrinkage in casting, but is tenacious,
and when drawn into wire has a tensile strength of ninety to one
hundred thousand pounds.
The following alloys, in which iron enters as a third element, are well
adapted for gun metal, being hard, tenacious, laminable, and ductile:
Cu Al Fe
Fe + (Al + Cu_{15}) = 0.9203 + 0.0267 + 0.0530
Fe + (Al + Cu_{9}) = 0.9399 + 0.0446 + 0.0149
Also a four-element alloy of
Cu Al Zn Fe
1. Fe + Zn + (Al + Cu_{12}) = 0.8386 + 0.0305 + 0.0712 + 0.0600
2. Fe + Zn + (Al + Cu_{15}) = 0.8666 + 0.0249 + 0.0588 + 0.0496
The tensile strength of the above alloys as drawn wire is 82,000 pounds
for the first, and 107,000 pounds for the second.
All of the alloys in which zinc or zinc and iron enter in place of
silver, the color is affected and the luster diminished.
With nickel and platinum for the third element, we have:
Cu Al Ni
Ni + 6 (Al + Cu_{6}) = 0.9129 + 0.0634 + 0.0237
Pl + 21 (Al + Cu_{6}) = 0.9117 + 0.0656 + 0.0225
Those alloys into which platinum is introduced are less affected by
acids than those in which silver takes the place of platinum; platinum
producing a higher luster than silver.
In the alloys of aluminum bronze with the more difficultly fusible
metals, it is preferable to fuse the bronze first, then add the other
metal in small shavings or wire; by this means the less fusible metal
absorbs the other without raising the heat of the furnace excessively.
Add the least fusible metal last, a little at a time, allowing the heat
of the melted metal to fall by degrees, which prevents boiling and
evaporation. The crucibles for mixing the alloys should be of plumbago
lined with a paste of lime.
Avoid sand crucibles, as silicium may be reduced and absorbed by the
aluminum, inducing brittleness. If found brittle, remelt with cryolite
as a flux, or stir the melted metal or alloy with a hard wood stick
that has been slightly charred.
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