Scientific American Supplement, No. 497, July 11, 1885Various
Science
Scientific American Supplement, No. 497, July 11, 1885
Various
Science -- Periodicals
Another means of separation was tried by precipitating the calcium
salts, from a solution of the potash soap. From the portion of the
calcium salts insoluble in alcohol, a fatty acid was obtained with a
melting point and composition almost identical with the melting point
and composition of palmitic acid. The aqueous portion of the separation
effected by water and ether was examined for the fatty acid. The lead
salts of the fatty acids were digested with ether, which dissolved out
the lead oleate. From this oleic acid was obtained. This was further
purified by forming the Boreum salt of oleic acid. The lead salts not
soluble in ether were decomposed by acid. The fatty acids set free were
saponified by carbonate of potassium. A fractional precipitation was
effected by adding lead acetate in successive portions; each portion
sufficient to precipitate one-fourth of all the acids present.
The acid obtained from the first fractionation had the melting point at
75 deg.-76 deg., indicating an acid either in carbon then stearic or palmitic
acids.
The acids obtained from the third fractionation had a melting point of
53 deg.-54 deg. C. This acid in composition and general properties was very
similar to that obtained by freezing the naphtha solution of the oil,
and is probably a mixture of stearic and palmitic acids. These acids,
being in combination with the bases of the oil, would be set free only
on saponifying the oil and subsequently decomposing with acid.
In conclusion, I should say that but a small proportion of the fatty
acids exist in the wool oil uncombined; that the proportion of oleic
acid is small, and can only be obtained in an oxidized condition; that
the main portion of the fatty acids is composed of stearic and palmitic
acids in nearly equal proportions; that the existence of a fatty acid,
containing a higher per cent. of carbon than those mentioned, is not
fully established.--_N.W. Shedd, M.I.T._
* * * * *
A NEW ABSORBENT FOR OXYGEN.
OTTO, BARON V.D. PFORDTEN.--The author makes use of a solution of
chromous chloride, which he prepares as follows:
He first heats chromic acid with concentrated hydrochloric acid, so
as to obtain a strong green solution of chromic chloride free from
chlorine. This is then reduced with zinc and hydrochloric acid. The blue
chromous chloride solution thus obtained is poured into a saturated
solution of sodium acetate in an atmosphere of carbonic acid. A
red precipitate of chromous acetate is formed, which is washed by
decantation in water containing carbonic acid. This salt is relatively
stable, and can be preserved for an indefinite time in a moist condition
in stoppered bottles filled with carbonic acid.
In this process the following precautions are to be observed:
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