Scientific American Supplement, No. 530, February 27, 1886Various
Science
Scientific American Supplement, No. 530, February 27, 1886
Various
Science -- Periodicals
Particularly important is the correct concentration. The most excellent
color matters make the plates oftentimes quite useless by an incorrect
proportion of concentration. If this should be too strong, the total
sensitiveness will sink (decrease); but when too weak, the color
sensitiveness is much reduced.
This fault, particularly, cannot be corrected during washing, but I have
mentioned, at the end, how such overcolored emulsion can be made of use
before wetting (flowing).
By the addition of some coloring matter to the emulsion, the light
sensitiveness of the film toward some individual colored rays is
increased, but the sensitiveness for the stronger refractive rays is, as
a rule, generally reduced. The result is a loss of the total
sensitiveness for white light. Color-sensitive plates are therefore less
sensitive to light than ordinary plates of the same origin.
The action of the coloring matter depends also very essentially upon the
emulsion. If the emulsion contains iodide of silver, it has a greater
sensitiveness for light blue and blue-green light. At all events, the
iodide combination must not amount to more than one or two per cent., a
small quantity of iodine acting much better upon the total sensitiveness
of the plates than can be obtained by pure bromide of silver emulsion.
Methyl violet, rose bengal, and azalein act perceptibly in 1/10000 per
cent. upon yellow sensitiveness. Eosine and its varieties, eosine yellow
shade, or eosine J, pyrosine J, erythrosine yellowish, may all be noted
as very good sensitizers for green, yellow-green, and eventually for
yellow. The bluish shades of eosine colors, on the contrary, have an
absorption band further in the yellow. This is also the case with the
blue shade eosine (eosine B) and the most bluish of all eosines, the
bengal rosa. Of both eosines, yellow shade and blue shade, the latter
gives a little more intensity.
Although the eosine permits a large limit in the quantity, it will reduce
the sensitiveness greatly in larger quantity.
If eosine solution is mixed with bromide of silver emulsion, which is
entirely free from nitrate of silver, no eosine silver can form; it acts,
therefore, only as an optical sensitizer.
Of the several kinds of cyanin, chlorosulphate, nitrate, and iodide, the
latter acts best, as stated by Eder.
Schumann has already said that one drop of cyanin solution, 1 to 2,500 to
6½ c. c. emulsion, already acted as sensitizing in orange; five to ten
drops cyanin. 1 to 1,500 to 15 c. c. emulsion, even gave red action.
Public-domain text, read in full here on John Shaqi.
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