Scientific American Supplement, No. 561, October 2, 1886Various
Science
Scientific American Supplement, No. 561, October 2, 1886
Various
Science -- Periodicals
It is in virtue of cohesion that a freely suspended drop of liquid
assumes the spherical form. If such a sphere be dropped on to the
surface of a liquid of higher specific gravity at rest, one obtains
what is called the cohesion figure of the substance of the drop. A
drop of oil, e.g., spreads out on the surface of water until it is a
circular thin film of concentric rings of different degrees of
thickness, each displaying the characteristic colors of thin plates.
The tenuity of the film increases; its cohesion is overcome; lakelets
are formed, and they merge into each other. The disintegrated portions
of the film now thicken, the colors vanish, and only islets of oil
remain. Some liquid drops of the same or higher sp. gr. than water do
not spread out in this fashion, but descend below the surface of the
liquid, and, in descending, assume a ring shape, which gradually
spreads out and breaks up into lesser rings. Such figures have been
termed submergence cohesion figures; they are vortex rings. I have
solidified such vortex rings in their first stage of formation. If
drops of melted sulphur, at a temperature above that of the viscous
state, be let fall into water, the drops will be solidified in the
effort to form the ring, and the circular button, thick in the rim and
thin in the center, may be regarded as a solidified vortex ring of
plastic sulphur.
_4. That a Submergence Cohesion Figure is a Vortex Ring._
It may be shown that the conditions of the formation of a submergence
cohesion figure are those which exist in the formation of an aerial
vortex. Those conditions in their greatest perfection are (1) a
spherical envelope of a different nature from the medium in which the
rings are produced; (2) a circular orifice opening into the medium;
and (3) a percussive impact on the part of the sphere opposite the
orifice. In the production of vortex rings of phosphorus pentoxide in
the making of phosphoreted hydrogen, the spherical envelope is water,
the orifice the portion of the bubble which opens into the air
immediately it rises to the surface, and the impact is furnished by
gravity. So, also, in the case of a submergence cohesion figure, the
spherical envelope is the air surrounding the drop, the orifice the
portion of it which first comes in contact with the liquid at rest;
and here again the impact is due to gravity more directly than in the
former case. These conditions are somewhat imperfectly copied in the
ordinary vortex box, which is usually cubical in form, with a circular
orifice in one side, and a covering of canvas on the opposite one,
which is hit with the fist.
* * * * *
[AMERICAN CHEMICAL JOURNAL.]
THE DETERMINATION OF NITRIC ACID BY THE ABSORPTION OF NITRIC OXIDE
IN A STANDARD SOLUTION OF PERMANGANATE OF POTASSIUM.
By H.N. MORSE and A.F. LINN.
Public-domain text, read in full here on John Shaqi.
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